Large deformation in filled networks of different architecture and its interpretation in terms of the van der Waals network model

摘要: The first quasi-static stretch of the two limiting systems filler loaded rubber have been investigated. One them is found by to matrix contacts only, other crosslinking permanently matrix. In this case filler-matrix are made adhesion. experimental results were described in terms an extended van der Waals approach. It illuminated that different contact (permanent bonds or adhesion) lead deformation mechanism, substantially affecting “reinforcement”. Moreover, induced local “field-modifications” due boundary value problem can be understood with Einstein-Smallwood approach independent kind contacts.