Theoretical Considerations and Equilibrium Conditions in Analytical Potentiometry. Computer Facilitated Mathematical Analysis of Equilibria in a Multicomponent System

摘要: A method entitled "analytical potentiometry" is described which permits the accurate determination of stability constants and distribution simultaneously existing complex species in multi-component systems. series computer programs are introduced to facilitate otherwise tedious mathematical analysis data. Besides simple binary systems, this capable dealing with mixed ligand coordination complexes can be adapted polynuclear For many metal ions, there no electrodes permitting those ions over a wide enough concentration range. This eliminates need for ion specific electrodes. The free determined indirectly by use weak base glass electrode. These features bear great significance resolving systems containing multiple cannot solved commonly known classical methods.