A possible role of free radicals in the oxidation of methane by Methylococcus capsulatus
作者： D.W. Hutchinson , R. Whittenbury , H. Dalton
DOI: 10.1016/S0022-5193(76)80123-3
关键词:
摘要: A mechanism involving free radicals is proposed for the oxidation of methane by Methylococcus capsulatus. Removal a hydrogen atom from can be effected oxygen in form hydroperoxide-iron complex. Subsequent steps methyl radical so formed to formaldehyde accounted known reactions. The substrates other than (e.g. dimethyl ether, carbon monoxide or ammonia) accommodated variations initial mechanism.
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