Cross-trienamines in Asymmetric Organocatalysis
作者： Kim Søholm Halskov , Tore Kiilerich Johansen , Rebecca L. Davis , Marianne Steurer , Frank Jensen
DOI: 10.1021/JA3068269
关键词:
摘要: Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates applied highly enantioselective Diels–Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds γ′-addition products, respectively. The nature of the transformations involved investigated by computational calculations NMR analysis.
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