Highly efficient near-infrared organic excimer electrophosphorescent diodes

作者: M. Cocchi , D. Virgili , V. Fattori , J. A. G. Williams , J. Kalinowski

DOI: 10.1063/1.2430926

关键词:

摘要: The authors report the fabrication of very high efficiency near-infrared (NIR) organic light-emitting diodes (LEDs) based on a series terdentate cyclometallated phosphorescent Pt(II) complexes PtLCl as emitting layer. LEDs exhibit exclusive NIR excimeric phosphorescence peaking between 705 and 720nm for three different ligands (L). Due to excimer emission quantum yields these Pt confinement recombination zone within layer, unusually external efficiencies from 9.8% 10.7% photons/electron forward light output exceeding 15mW∕cm2 were achieved.

参考文章(15)
R. G. Sun, Y. Z. Wang, Q. B. Zheng, H. J. Zhang, A. J. Epstein, 1.54 μm infrared photoluminescence and electroluminescence from an erbium organic compound Journal of Applied Physics. ,vol. 87, pp. 7589- 7591 ,(2000) , 10.1063/1.373027
V. Bulović, V. B. Khalfin, G. Gu, P. E. Burrows, D. Z. Garbuzov, S. R. Forrest, Weak microcavity effects in organic light-emitting devices Physical Review B. ,vol. 58, pp. 3730- 3740 ,(1998) , 10.1103/PHYSREVB.58.3730
J. Kalinowski, L. C. Palilis, W. H. Kim, Z. H. Kafafi, Determination of the width of the carrier recombination zone in organic light-emitting diodes Journal of Applied Physics. ,vol. 94, pp. 7764- 7767 ,(2003) , 10.1063/1.1624477
J. A. Gareth Williams, Andrew Beeby, E. Stephen Davies, Julia A. Weinstein, Claire Wilson, An Alternative Route to Highly Luminescent Platinum(II) Complexes: Cyclometalation with N∧C∧N-Coordinating Dipyridylbenzene Ligands Inorganic Chemistry. ,vol. 42, pp. 8609- 8611 ,(2003) , 10.1021/IC035083+
Evan L. Williams, Jian Li, Ghassan E. Jabbour, Organic light-emitting diodes having exclusive near-infrared electrophosphorescence Applied Physics Letters. ,vol. 89, pp. 083506- ,(2006) , 10.1063/1.2335275
Nir Tessler, Vlad Medvedev, Miri Kazes, ShiHai Kan, Uri Banin, Efficient Near-Infrared Polymer Nanocrystal Light-Emitting Diodes Science. ,vol. 295, pp. 1506- 1508 ,(2002) , 10.1126/SCIENCE.1068153
Brian D’Andrade, Stephen R. Forrest, Formation of triplet excimers and dimers in amorphous organic thin films and light emitting devices principles and practice of constraint programming. ,vol. 286, pp. 321- 335 ,(2003) , 10.1016/S0301-0104(02)00921-7
Sarah J. Farley, David L. Rochester, Amber L. Thompson, Judith A. K. Howard, J. A. Gareth Williams, Controlling Emission Energy, Self-Quenching, and Excimer Formation in Highly Luminescent N∧C∧N-Coordinated Platinum(II) Complexes Inorganic Chemistry. ,vol. 44, pp. 9690- 9703 ,(2005) , 10.1021/IC051049E
C. W. Tang, S. A. VanSlyke, Organic Electroluminescent Diodes Applied Physics Letters. ,vol. 51, pp. 913- 915 ,(1987) , 10.1063/1.98799