Dinuclear Complexes and a One-dimensional Chain Involving Difunctional Ligands Containing the Acetylacetonate Functionality
作者： Joseph B. Lambert , Zhongqiang Liu
DOI: 10.1007/S10870-007-9224-7
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摘要: Systems containing two acetylacetonate (acac) ligands separated by an aromatic spacer (1–3) react with Cu(II) in the presence of bidentate nitrogen to form crystalline, capped, dinuclear (zero-dimensional) structures (6–8). Noncovalent interactions between stacked on adjacent molecules 7 and 8 produce one-dimensional chains crystal. Molecules 1–3 fail covalent metal-organic bonding reaction alone. System 5, which contains a single acac ligand pyridyl nitrogen, forms chain (9). The ribbon passes from back acac. phenanthroline 9 provide noncovalent crystal two-dimensional layered structure. Dinuclear Complexes One-dimensional Chain Involving Difunctional Ligands Containing Acetylacetonate Functionality Joseph B. Lambert Zhongqiang Liu Two structures, whereas linked pyridine noncovalently bonded structure
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