Adsorption Thermodynamics, Kinetics and Isosteric Heat of Adsorption of Rhodamin-B onto Granular Activated Carbon
作者： Jong Jib Lee
关键词:
摘要: The adsorption of Rhodamine-B dye using granular activated carbon from aqueous solution was investigated. Adsorption experiments were carried out as a function the adsorbent dose, pH initial concentration, contact time and temperature. equilibrium data showed good fit to Langmuir isotherm model. Based on estimated separation factor (RL = 0.0164~0.0314), our process could be employed an effective treatment method. kinetics followed pseudo first order Also, negative values Gibbs free energy (-4.51~-13.44 kJ/mol) positive enthalpy (128.97 indicated that spontaneous endothermic process. isosteric heat increased with increase in surface loading indicating lateral interactions between adsorbed molecules.
koreascience.or.kr参考文章(25)
Sun-Young An, Sang-Ki Min, In-Ho Cha, Yong-Lark Choi, Young-Su Cho, Cherol-Ho Kim, Young-Choon Lee, Decolorization of triphenylmethane and azo dyes by Citrobacter sp. Biotechnology Letters. ,vol. 24, pp. 1037- 1040 ,(2002) , 10.1023/A:1015610018103
Dong Wan, Wenbing Li, Guanghua Wang, Kun Chen, Lulu Lu, Qin Hu, Adsorption and heterogeneous degradation of rhodamine B on the surface of magnetic bentonite material Applied Surface Science. ,vol. 349, pp. 988- 996 ,(2015) , 10.1016/J.APSUSC.2015.05.004
Monika Jain, V.K. Garg, K. Kadirvelu, Chromium(VI) removal from aqueous system using Helianthus annuus (sunflower) stem waste Journal of Hazardous Materials. ,vol. 162, pp. 365- 372 ,(2009) , 10.1016/J.JHAZMAT.2008.05.048
T.S. Anirudhan, P.G. Radhakrishnan, Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto a new cation exchanger derived from tamarind fruit shell The Journal of Chemical Thermodynamics. ,vol. 40, pp. 702- 709 ,(2008) , 10.1016/J.JCT.2007.10.005
Yang Zhang, Jilin Wang, Lulu Wang, Ruijiang Feng, Fan Zhang, Study on adsorption properties of QCS/PS-G8-2-8 anion exchange membrane for Rhodamine B Journal of Molecular Structure. ,vol. 1089, pp. 116- 123 ,(2015) , 10.1016/J.MOLSTRUC.2015.02.041
C. Namasivayam, R. T. Yamuna, Removal of congo red from aqueous solutions by biogas waste slurry Journal of Chemical Technology & Biotechnology. ,vol. 53, pp. 153- 157 ,(2007) , 10.1002/JCTB.280530208
Mehmet Doğan, Mahir Alkan, Özkan Demirbaş, Yasemin Özdemir, Cengiz Özmetin, Adsorption kinetics of maxilon blue GRL onto sepiolite from aqueous solutions Chemical Engineering Journal. ,vol. 124, pp. 89- 101 ,(2006) , 10.1016/J.CEJ.2006.08.016
M. Ghaedi, H. Hossainian, M. Montazerozohori, A. Shokrollahi, F. Shojaipour, M. Soylak, M.K. Purkait, A novel acorn based adsorbent for the removal of brilliant green Desalination. ,vol. 281, pp. 226- 233 ,(2011) , 10.1016/J.DESAL.2011.07.068
Hem Lata, Suman Mor, V.K. Garg, R.K. Gupta, Removal of a dye from simulated wastewater by adsorption using treated parthenium biomass Journal of Hazardous Materials. ,vol. 153, pp. 213- 220 ,(2008) , 10.1016/J.JHAZMAT.2007.08.039
C. Namasivayam, D. Kavitha, Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste Dyes and Pigments. ,vol. 54, pp. 47- 58 ,(2002) , 10.1016/S0143-7208(02)00025-6