Mixed adsorption at mercury/solution interfaces
作者： S. Lakshmanan , S.K. Rangarajan
DOI: 10.1016/S0022-0728(70)80208-X
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摘要: Summary A thermodynamic analysis is given of the electrocapillary equation suitable for evaluation individual surface excesses at inner planes two specifically adsorbed anions from a mixture containing these along with common cation. This takes into account variation activity coefficients salts in mixture. The problem interpreting data obtained absence cation-sensitive electrode considered and appropriate expressions are given.
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sci-hub.se 参考文章(9)
Henri D. Hurwitz, Direct determination of the surface excess of specifically adsorbed ions on mercury Journal of Electroanalytical Chemistry. ,vol. 10, pp. 35- 41 ,(1965) , 10.1016/0022-0728(65)85013-6
R. D. Lanier, Activity Coefficients of Sodium Chloride in Aqueous Three-Component Solutions by Cation-Sensitive Glass Electrodes1a The Journal of Physical Chemistry. ,vol. 69, pp. 3992- 3998 ,(1965) , 10.1021/J100895A058
Edward Dutkiewicz, Roger Parsons, The adsorption of iodide ion from aqueous KI + KF of constant ionic strength Journal of Electroanalytical Chemistry (1959). ,vol. 11, pp. 100- 110 ,(1966) , 10.1016/0022-0728(66)80069-4
David C. Grahame, Diffuse Double Layer Theory for Electrolytes of Unsymmetrical Valence Types The Journal of Chemical Physics. ,vol. 21, pp. 1054- 1060 ,(1953) , 10.1063/1.1699109
E.A. Guggenheim, L. The specific thermodynamic properties of aqueous solutions of strong electrolytes Philosophical Magazine Series 1. ,vol. 19, pp. 588- 643 ,(1935) , 10.1080/14786443508561403
David C. Grahame, The Electrical Double Layer and the Theory of Electrocapillarity. Chemical Reviews. ,vol. 41, pp. 441- 501 ,(1947) , 10.1021/CR60130A002
Richard Payne, Structure of the Electrical Double Layer at a Mercury Electrode in the Presence of Adsorbed Perchlorate Ions The Journal of Physical Chemistry. ,vol. 69, pp. 4113- 4123 ,(1965) , 10.1021/J100782A011
Richard Payne, Specific adsorption of chloride ions at the mercury/aqueous solution interface Transactions of The Faraday Society. ,vol. 64, pp. 1638- 1655 ,(1968) , 10.1039/TF9686401638
S. Lakshamanan, S.K. Rangarajan, Activity coefficients in mixed electrolytes: a note on Guggenheim's relation Journal of Electroanalytical Chemistry. ,vol. 27, pp. 170- 174 ,(1970) , 10.1016/S0022-0728(70)80216-9