Densities and thermal expansions of (water + tetrahydrofuran) mixtures within the temperature range from (274.15 to 333.15) K at atmospheric pressure

作者: Gennadiy I. Egorov , Dmitriy M. Makarov

DOI: 10.1016/J.MOLLIQ.2020.113105

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摘要: Abstract The mixture {water (1) + tetrahydrofuran (2)} densities have been measured over the whole composition range at temperatures between (274.15 and 333.15 K) atmospheric pressure using vibration type densimeter. Values of excess molar volume isobaric thermal expansion as well apparent/partial volumes (down infinite dilution) for water tetrahydrofuran (THF) calculated. It is shown that formation + THF occurs with decreasing its under all temperatures. Concentration dependences partial are characterized by presence extreme regions. Standard (limiting) increase temperature rising. Increase in both content influence on value same way.

参考文章(93)
George Wypych, Handbook of Solvents ,(2000)
Ángel Piñeiro, Pilar Brocos, Alfredo Amigo, Mercedes Pintos, Ramón Bravo, Refractive Indexes of Binary Mixtures of Tetrahydrofuran with 1-Alkanols at 25°C and Temperature Dependence of n and ρ for the Pure Liquids Journal of Solution Chemistry. ,vol. 31, pp. 369- 380 ,(2002) , 10.1023/A:1015807331250
B. Meuthen, M. v. Stackelberg, Feste Gashydrate. VII. Hydrate wasserlöslicher Äther Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 62, pp. 130- 131 ,(1958) , 10.1002/BBPC.19580620206
Jeffery B. Klauda, Mikhail A. Anisimov, Jan Leys, Deepa Subramanian, Thermodynamic anomalies and structural fluctuations in aqueous solutions of tertiary butyl alcohol arXiv: Soft Condensed Matter. ,(2013)
M. N. Rodnikova, M. A. Gunina, D. M. Makarov, G. I. Egorov, T. M. Val’kovskaya, Molar volumes of aqueous and ethylene glycol solutions of tetrahydrofuran Russian Journal of Physical Chemistry A. ,vol. 85, pp. 1676- 1678 ,(2011) , 10.1134/S003602441109024X
Koh Yoshida, Peter Westh, Akira Inaba, Motohiro Nakano, Yoshikata Koga, Third derivative thermodynamic quantities of aqueous tetrahydrofuran at 25 °C Journal of Molecular Liquids. ,vol. 202, pp. 40- 45 ,(2015) , 10.1016/J.MOLLIQ.2014.11.029
O. D. Bonner, Y. S. Choi, Hydrogen bonding of water in organic solvents. 1 The Journal of Physical Chemistry. ,vol. 78, pp. 1723- 1727 ,(1974) , 10.1021/J100610A009
Phillip J. Back, Lawrence A. Woolf, (p,V,T,x) measurements for tetrahydrofuran and {xC4H8O + (1−x)H2O} The Journal of Chemical Thermodynamics. ,vol. 30, pp. 353- 364 ,(1998) , 10.1006/JCHT.1997.0310