Chemical equilibrium in argon: Anomaly of density dependence of dimerization reaction in the medium density region

摘要: We studied the dimerization equilibrium of 2‐methyl‐2‐nitrosopropane in argon at 25.0 °C from about 500 to 1200 kg m−3. It is clarified that simplest solvent, argon, there exists a definite difference density dependence constant between high and medium regions. In region, shows sizable increase with solvent as liquid phase. Near critical density, however, little dependence.