Syntheses and Crystal Structures of Three Metal‐Organic Frameworks Constructed from a C3‐Symmetrical Tricarboxylic Acid

作者: Khalid Alfooty , Yabing He , Frank R. Fronczek , Banglin Chen

DOI: 10.1002/ZAAC.201500060

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摘要: Three coordination polymers were synthesized by solvothermal reaction of a C3‐symmetrical organic ligand and metal ions (Zn2+, Cd2+, Mn2+). Single‐crystal X‐ray diffraction studies revealed that the compounds consist of trinuclear secondary building blocks connected by the organic linkers to form two‐dimensional layers, which are packed together to form the final architectures, although they crystallized in the different space groups.

参考文章(30)
Omar K. Farha, A. Özgür Yazaydın, Ibrahim Eryazici, Christos D. Malliakas, Brad G. Hauser, Mercouri G. Kanatzidis, SonBinh T. Nguyen, Randall Q. Snurr, Joseph T. Hupp, De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities Nature Chemistry. ,vol. 2, pp. 944- 948 ,(2010) , 10.1038/NCHEM.834
Liqing Ma, David J. Mihalcik, Wenbin Lin, Highly porous and robust 4,8-connected metal-organic frameworks for hydrogen storage. Journal of the American Chemical Society. ,vol. 131, pp. 4610- 4612 ,(2009) , 10.1021/JA809590N
Yong Yan, Sihai Yang, Alexander J. Blake, Martin Schröder, Studies on metal-organic frameworks of Cu(II) with isophthalate linkers for hydrogen storage. Accounts of Chemical Research. ,vol. 47, pp. 296- 307 ,(2014) , 10.1021/AR400049H
Eleni J. Kyprianidou, Giannis S. Papaefstathiou, Manolis J. Manos, Anastasios J. Tasiopoulos, A flexible Cd2+ metal organic framework with a unique (3,3,6)-connected topology, unprecedented secondary building units and single crystal to single crystal solvent exchange properties CrystEngComm. ,vol. 14, pp. 8368- 8373 ,(2012) , 10.1039/C2CE25913C
Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro, Functional Porous Coordination Polymers Angewandte Chemie International Edition. ,vol. 43, pp. 2334- 2375 ,(2004) , 10.1002/ANIE.200300610
Banglin Chen, Mohamed Eddaoudi, ST Hyde, Michael O'Keeffe, OM Yaghi, Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores Science. ,vol. 291, pp. 1021- 1023 ,(2001) , 10.1126/SCIENCE.1056598
Vincent Guillerm, Łukasz J. Weseliński, Youssef Belmabkhout, Amy J. Cairns, Valerio D'Elia, Łukasz Wojtas, Karim Adil, Mohamed Eddaoudi, Discovery and introduction of a (3,18)-connected net as an ideal blueprint for the design of metal-organic frameworks. Nature Chemistry. ,vol. 6, pp. 673- 680 ,(2014) , 10.1038/NCHEM.1982
Hee K Chae, Diana Y Siberio-Pérez, Jaheon Kim, YongBok Go, Mohamed Eddaoudi, Adam J Matzger, Michael O'keeffe, Omar M Yaghi, Materials Design and Discovery Group, None, A route to high surface area, porosity and inclusion of large molecules in crystals Nature. ,vol. 427, pp. 523- 527 ,(2004) , 10.1038/NATURE02311
Yuanjing Cui, Yanfeng Yue, Guodong Qian, Banglin Chen, Luminescent Functional Metal–Organic Frameworks Chemical Reviews. ,vol. 112, pp. 1126- 1162 ,(2012) , 10.1021/CR200101D
Yabing He, Bin Li, Michael O'Keeffe, Banglin Chen, Multifunctional metal-organic frameworks constructed from meta-benzenedicarboxylate units. Chemical Society Reviews. ,vol. 43, pp. 5618- 5656 ,(2014) , 10.1039/C4CS00041B