Electroluminescence from heterostructures of poly(phenylene vinylene) and inorganic CdSe nanocrystals

作者: Hedi Mattoussi , Leonard H. Radzilowski , Bashir O. Dabbousi , Edwin L. Thomas , Moungi G. Bawendi

DOI: 10.1063/1.367978

关键词:

摘要: Electroluminescence (EL) and photoluminescence (PL) from heterostructure thin films made of organic poly (phenylene vinylene), PPV, inorganic semiconductor CdSe nanocrystals are investigated. In these devices, the PPV structure is built next to an indium tin oxide anode, using technique molecular layer-by-layer sequential adsorption, serves primarily as hole transport layer. The layer, adjacent Al electrode, spin cast nanocrystals, passivated with either groups or a wider band gap semiconductor, e.g., ZnS in present case. We find that electroluminescence signal almost exclusively generated within very weak contribution layer at higher applied voltage. performance devices influenced by thickness dot Lifetime tests reveal promising stability, operating continuously over 50–100 h. Values external quantum efficiency, η...

参考文章(44)
S. Karg, M. Meier, W. Riess, Light-emitting diodes based on poly-p-phenylene-vinylene: I. Charge-carrier injection and transport Journal of Applied Physics. ,vol. 82, pp. 1951- 1960 ,(1997) , 10.1063/1.366003
J.H. Cheng, A.F. Fou, M.F. Rubner, Molecular self-assembly of conducting polymers Thin Solid Films. ,vol. 244, pp. 985- 989 ,(1994) , 10.1016/0040-6090(94)90616-5
A. C. Fou, O. Onitsuka, M. Ferreira, M. F. Rubner, B. R. Hsieh, Fabrication and properties of light‐emitting diodes based on self‐assembled multilayers of poly(phenylene vinylene) Journal of Applied Physics. ,vol. 79, pp. 7501- 7509 ,(1996) , 10.1063/1.362421
I. D. Parker, Carrier tunneling and device characteristics in polymer light‐emitting diodes Journal of Applied Physics. ,vol. 75, pp. 1656- 1666 ,(1994) , 10.1063/1.356350
C. B. Murray, D. J. Norris, M. G. Bawendi, Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites Journal of the American Chemical Society. ,vol. 115, pp. 8706- 8715 ,(1993) , 10.1021/JA00072A025
B. Hu, Z. Yang, F. E. Karasz, Electroluminescence of pure poly(N‐vinylcarbazole) and its blends with a multiblock copolymer Journal of Applied Physics. ,vol. 76, pp. 2419- 2422 ,(1994) , 10.1063/1.358458
Margaret A. Hines, Philippe Guyot-Sionnest, Synthesis and Characterization of Strongly Luminescing ZnS-Capped CdSe Nanocrystals The Journal of Physical Chemistry. ,vol. 100, pp. 468- 471 ,(1996) , 10.1021/JP9530562
Xiaogang Peng, Michael C. Schlamp, Andreas V. Kadavanich, A. P. Alivisatos, Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility Journal of the American Chemical Society. ,vol. 119, pp. 7019- 7029 ,(1997) , 10.1021/JA970754M
Nynke G. Hoogeveen, Martien A. Cohen Stuart, Gerard J. Fleer, Marcel R. Böhmer, Formation and stability of multilayers of polyelectrolytes. Langmuir. ,vol. 12, pp. 3675- 3681 ,(1996) , 10.1021/LA951574Y
N.F. Borrelli, D.W. Smith, Quantum confinement of PbS microcrystals in glass Journal of Non-crystalline Solids. ,vol. 180, pp. 25- 31 ,(1994) , 10.1016/0022-3093(94)90393-X