Polymer electrolytes formed from oxymethylene-linked poly (oxyethylene) and alkali metal perchlorates studied by Raman spectroscopy

作者: K VIRAS , J THATCHER , C NICHOLAS , C BOOTH

DOI: 10.1016/0167-2738(94)90234-8

关键词:

摘要: Abstract Raman spectra were recorded for mixtures of oxymethylene-linked poly (oxyethylene), [oxymethylene-oligo (oxyethylene)], with sodium and lithium perchlorate in various molar ratios. The effect salt concentration on the bands at 250–310 cm −1 ca. 860 is discussed.

参考文章(26)
James R. Scherer, Robert G. Snyder, Raman spectra of liquid n‐alkanes. II. Longitudinal acoustic modes and the gauche–trans energy difference Journal of Chemical Physics. ,vol. 72, pp. 5798- 5808 ,(1980) , 10.1063/1.439102
Yozo Chatani, Yasuhiro Fujii, Tetsuya Takayanagi, Atsuya Honma, Structures of two crystal forms of poly(ethylene oxide)-sodium thiocyanate complex with molar ratios of 3:1 and 1:1 Polymer. ,vol. 31, pp. 2238- 2244 ,(1990) , 10.1016/0032-3861(90)90308-L
R. Dupon, B. L. Papke, M. A. Ratner, D. H. Whitmore, D. F. Shriver, Influence of ion pairing on cation transport in the polymer electrolytes formed by poly(ethylene oxide) with sodium tetrafluoroborate and sodium tetrahydroborate Journal of the American Chemical Society. ,vol. 104, pp. 6247- 6251 ,(1982) , 10.1021/JA00387A014
G. Gordon Cameron, Malcolm D. Ingram, Graham A. Sorrie, The mechanism of conductivity of liquid polymer electrolytes Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 83, pp. 3345- 3353 ,(1987) , 10.1039/F19878303345
B. L. Papke, M. A. Ratner, D. F. Shriver, Vibrational Spectroscopic Determination of Structure and Ion Pairing in Complexes of Poly(ethylene oxide) with Lithium Salts Journal of The Electrochemical Society. ,vol. 129, pp. 1434- 1438 ,(1982) , 10.1149/1.2124179
James R. MacCallum, Anthony S. Tomlin, Colin A. Vincent, An investigation of the conducting species in polymer electrolytes European Polymer Journal. ,vol. 22, pp. 787- 791 ,(1986) , 10.1016/0014-3057(86)90017-0
Hideo Takeuchi, Takaki Arai, Issei Harada, Structures of 18-crown-6, 15-crown-5 and their metal complexes in methanol solution as studied by Raman spectroscopy Journal of Molecular Structure. ,vol. 146, pp. 197- 212 ,(1986) , 10.1016/0022-2860(86)80293-9