Alkane complexes as intermediates in C-H bond activation reactions

摘要: The rearrangements of alkyl deuteride complexes are monitored and a kinetic model used to extract the rate constants for fundamental processes involving unseen alkane σ-complexes. Isotope effects C-H C-D bond formation cleavage have been measured permit these determinations. relative rates available an σ-complex (C-H oxidative cleavage, dissociation, migration adjacent bond) determined methane, ethane, propane, butane, pentane, hexane.