Forensic Applications of Portable X-ray Fluorescence Spectrometer: Glass Samples

作者: Shih-Yuan Cheng , Yung-Fou Chen , Chih-Chun Jean Huang

DOI: 10.1002/JCCS.201400229

关键词:

摘要: Portable X-ray Fluorescence Spectrometer (PXRF) is a qualitative and semi-quantitative elemental analysis method. Recently, many researches using PXRF in the of materials have been reported. However, has not extensively applied forensic science, thus this study devoted to demonstrate utility technique through rapid glass samples for preliminary discrimination. Major elements such as Si, O, Ca, Al, Na, well traces Sr, Rb, K, Fe Sn, 25 were analyzed by PXRF. The amounts some elements, Fe, Zr, vary different samples, while other Th, are consistent most tested samples. results show that we can discriminate 98.31 % 7,500 pair-wise comparisons created from This establishes new method glass, which shows potential be further discrimination field.

参考文章(17)
Ju Chou, Garret Clement, Bradley Bursavich, Don Elbers, Baobao Cao, Weilie Zhou, Rapid detection of toxic metals in non-crushed oyster shells by portable X-ray fluorescence spectrometry. Environmental Pollution. ,vol. 158, pp. 2230- 2234 ,(2010) , 10.1016/J.ENVPOL.2010.02.015
Peter T. Palmer, Richard Jacobs, Peter E. Baker, Kelly Ferguson, Siri Webber, Use of field-portable XRF analyzers for rapid screening of toxic elements in FDA-regulated products. Journal of Agricultural and Food Chemistry. ,vol. 57, pp. 2605- 2613 ,(2009) , 10.1021/JF803285H
A. van Es, J. de Koeijer, G. van der Peijl, Discrimination of document paper by XRF, LA–ICP–MS and IRMS using multivariate statistical techniques Science & Justice. ,vol. 49, pp. 120- 126 ,(2009) , 10.1016/J.SCIJUS.2009.03.006
Dennis J Kalnicky, Raj Singhvi, Field portable XRF analysis of environmental samples. Journal of Hazardous Materials. ,vol. 83, pp. 93- 122 ,(2001) , 10.1016/S0304-3894(00)00330-7
Jacob I Trombka, Jeffrey Schweitzer, Carl Selavka, Mark Dale, Norman Gahn, Samuel Floyd, James Marie, Maritza Hobson, Jerry Zeosky, Ken Martin, Timothy McClannahan, Pamela Solomon, Elyse Gottschang, Crime scene investigations using portable, non-destructive space exploration technology Forensic Science International. ,vol. 129, pp. 1- 9 ,(2002) , 10.1016/S0379-0738(02)00079-8
Benjamin E. Naes, Sayuri Umpierrez, Scott Ryland, Cleon Barnett, Jose R. Almirall, A comparison of laser ablation inductively coupled plasma mass spectrometry, micro X-ray fluorescence spectroscopy, and laser induced breakdown spectroscopy for the discrimination of automotive glass Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 63, pp. 1145- 1150 ,(2008) , 10.1016/J.SAB.2008.07.005
Philip J Potts, Margaret West, None, Portable x-ray fluorescence spectrometry : capabilities for in situ analysis Royal Society of Chemistry. ,(2008) , 10.1039/9781847558640
J.H. Macek, James Sternberg, Hyperspherical adiabatic potentials for 3-fermion threshold interactions Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 241, pp. 1- 4 ,(2005) , 10.1016/J.NIMB.2005.07.228
Tanja Radu, Dermot Diamond, Comparison of soil pollution concentrations determined using AAS and portable XRF techniques. Journal of Hazardous Materials. ,vol. 171, pp. 1168- 1171 ,(2009) , 10.1016/J.JHAZMAT.2009.06.062