Electrochemical and structural performances of Li[Ni0.133Li0.2Co0.133Mn0.533]O2 material during different cycle potential windows

作者: Jun-Qiang Li , Yun-Jie Yang , Jing Pang

DOI: 10.1007/S12598-015-0562-X

关键词:

摘要: The effects of cycle potential window on electrochemical behaviors, structural characteristics, and surface changes in Li[Ni0.133Li0.2Co0.133Mn0.533]O2 (or 0.5Li2MnO3·0.5Li(Co0.333Ni0.333Mn0.333)O2) lithium-ion battery were investigated. Two flat charge plateaus, ~3.9 ~4.5 V, are observed the initial curves cells. Sharp specific capacity columbic efficiency presented at V during first cycle. XRD peaks show an obvious shift with increase cutoff potential. When is above 4.4 performance decreases potentials. A film composition C O elements cycled composite particle.

参考文章(33)
Francis Amalraj, Daniela Kovacheva, Michael Talianker, Leila Zeiri, Judith Grinblat, Nicole Leifer, Gil Goobes, Boris Markovsky, Doron Aurbach, Synthesis of Integrated Cathode Materials xLi2MnO3⋅ ( 1 − x ) LiMn1 / 3Ni1 / 3Co1 / 3O2 ( x = 0.3 , 0.5 , 0.7 ) and Studies of Their Electrochemical Behavior Journal of The Electrochemical Society. ,vol. 157, ,(2010) , 10.1149/1.3463782
JM Zheng, ZR Zhang, XB Wu, ZX Dong, Z Zhu, Y Yang, None, The Effects of AlF3 Coating on the Performance of Li [ Li0.2Mn0.54Ni0.13Co0.13 ] O2 Positive Electrode Material for Lithium-Ion Battery Journal of The Electrochemical Society. ,vol. 155, ,(2008) , 10.1149/1.2966694
Lucille Bodenes, Rémi Dedryvère, Hervé Martinez, Florent Fischer, Cécile Tessier, Jean-Paul Pérès, Lithium-Ion Batteries Working at 85°C: Aging Phenomena and Electrode/Electrolyte Interfaces Studied by XPS Journal of The Electrochemical Society. ,vol. 159, ,(2012) , 10.1149/2.061210JES
Naoaki Yabuuchi, Kazuhiro Yoshii, Seung-Taek Myung, Izumi Nakai, Shinichi Komaba, Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li2MnO3−LiCo1/3Ni1/3Mn1/3O2 Journal of the American Chemical Society. ,vol. 133, pp. 4404- 4419 ,(2011) , 10.1021/JA108588Y
S.-H. Park, S.-H. Kang, I. Belharouak, Y.K. Sun, K. Amine, Physical and electrochemical properties of spherical Li1+x(Ni1/3Co1/3Mn1/3)1−xO2 cathode materials Journal of Power Sources. ,vol. 177, pp. 177- 183 ,(2008) , 10.1016/J.JPOWSOUR.2007.10.062
Pierre Strobel, Bernadette Lambert-Andron, Crystallographic and magnetic structure of Li2MnO3 Journal of Solid State Chemistry. ,vol. 75, pp. 90- 98 ,(1988) , 10.1016/0022-4596(88)90305-2
Christopher S. Johnson, Naichao Li, Christina Lefief, Michael M. Thackeray, Anomalous capacity and cycling stability of xLi2MnO3 · (1 − x)LiMO2 electrodes (M = Mn, Ni, Co) in lithium batteries at 50 °C Electrochemistry Communications. ,vol. 9, pp. 787- 795 ,(2007) , 10.1016/J.ELECOM.2006.11.006
Debasish Mohanty, Sergiy Kalnaus, Roberta A. Meisner, Kevin J. Rhodes, Jianlin Li, E. Andrew Payzant, David L. Wood, Claus Daniel, Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction Journal of Power Sources. ,vol. 229, pp. 239- 248 ,(2013) , 10.1016/J.JPOWSOUR.2012.11.144