Electrochemistry in pyridine-IV. Chemical and electrochemical reduction of pyridine
作者： A. Cisak , P.J. Elving
DOI: 10.1016/0013-4686(65)80005-6
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摘要: The cathodic polarographic wave observed for solutions of AlCl, in pyridine is due not to reduction Al(III), but the solvent, which process Al(II1) plays an essential role, apparently by polarizing through formation a Lewis acid-base adduct with nitrogen. Macroscale electrolysis at mercury cathode results and formation, after hydrolysis air oxidation, complex mixture or copolymer unsaturated polyamines polyamides probably containing such I 1
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