DOI: 10.1021/MA0482821
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摘要: We propose a simple theory describing the influence of nanoparticles on thermodynamics binary polymer mixture. In particular, we consider case in which preferentially segregate into one polymeric components. Depending particle radius Rp and degree polymerization N, addition can either promote or hinder mixing polymers. calculate how shifts spinodal blend. These results help to improve understanding recent simulations dynamics polymer/particle mixtures.