Electrochemical treatment of humic acid using particle electrodes ensembled by ordered mesoporous carbon
作者： Xue Li , Wenwen Zhang , Di Xie , Xiaoyu Wang , Wenjian Ye
DOI: 10.1007/S11356-018-2193-X
关键词:
摘要: In order to degrade the macromolecular pollutant of humic acid, powder ordered mesoporous carbon (POMC, average pore diameter 4.29 nm) was first applied for preparing granular OMC (GOMC, Φ × H = 4 × 3–6 mm) as electrodes in a continuous three-dimensional (3D) electrochemical system. The POMC synthesized by hard-templating method and characterized using scanning electron microscopy (SEM), transmission (TEM), particle size distribution, N2 adsorption/desorption technology, Fourier-transform infrared (FT-IR). effects degradation parameters, such current hydraulic retention time (HRT), were investigated, mechanism HA explored well. results indicated that efficiency HA, chemical oxygen demand (COD), total organic (TOC) reached 95.3, 86.2, 62.7%, respectively, under initial 100 mg/L, 0.2 A, HRT 130 min. detection paramagnetic resonance (EPR) showed plenty ˙OH generated on GOMC electrodes, which made 3D system more effective than conventional two-dimensional (2D) cyclic voltammetry curves reactions materials surface included both direct oxidation reduction.
springer.com
sci-hub.se 参考文章(56)
Eric Lichtfouse, Jan Schwarzbauer, Didier Robert, Stephanie N Dudd, Introduction to Environmental Chemistry Letters Environmental Chemistry Letters. ,vol. 1, pp. 1- 1 ,(2003) , 10.1007/S10311-003-0021-Z
Fengling Liu, Zhaoyi Xu, Haiqin Wan, Yuqiu Wan, Shourong Zheng, Dongqiang Zhu, Enhanced adsorption of humic acids on ordered mesoporous carbon compared with microporous activated carbon Environmental Toxicology and Chemistry. ,vol. 30, pp. 793- 800 ,(2011) , 10.1002/ETC.450
Danious P. Sounthararajah, Paripurnanda Loganathan, Jaya Kandasamy, Saravanamuthu Vigneswaran, Column studies on the removal of dissolved organic carbon, turbidity and heavy metals from stormwater using granular activated carbon Desalination and Water Treatment. ,vol. 57, pp. 5045- 5055 ,(2016) , 10.1080/19443994.2014.999717
Juqin Zeng, Carlotta Francia, Mihaela A. Dumitrescu, Alessandro H. A. Monteverde Videla, Vijaykumar S. Ijeri, Stefania Specchia, Paolo Spinelli, Electrochemical Performance of Pt-Based Catalysts Supported on Different Ordered Mesoporous Carbons (Pt/OMCs) for Oxygen Reduction Reaction Industrial & Engineering Chemistry Research. ,vol. 51, pp. 7500- 7509 ,(2012) , 10.1021/IE2016619
K. S. W. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) Pure and Applied Chemistry. ,vol. 57, pp. 603- 619 ,(1985) , 10.1351/PAC198557040603
Zhaoyang Wang, Jingyao Qi, Yan Feng, Ke Li, Xin Li, Preparation of catalytic particle electrodes from steel slag and its performance in a three-dimensional electrochemical oxidation system Journal of Industrial and Engineering Chemistry. ,vol. 20, pp. 3672- 3677 ,(2014) , 10.1016/J.JIEC.2013.12.065
Xinbo Wu, Xiaoqing Yang, Dingcai Wu, Ruowen Fu, Feasibility study of using carbon aerogel as particle electrodes for decoloration of RBRX dye solution in a three-dimensional electrode reactor Chemical Engineering Journal. ,vol. 138, pp. 47- 54 ,(2008) , 10.1016/J.CEJ.2007.05.027
Zakaria Tabti, Ramiro Ruiz-Rosas, César Quijada, Diego Cazorla-Amorós, Emilia Morallón, Tailoring the surface chemistry of activated carbon cloth by electrochemical methods. ACS Applied Materials & Interfaces. ,vol. 6, pp. 11682- 11691 ,(2014) , 10.1021/AM502475V
D. Zhao, Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Science. ,vol. 279, pp. 548- 552 ,(1998) , 10.1126/SCIENCE.279.5350.548
W. Tanthapanichakoon, P. Ariyadejwanich, P. Japthong, K. Nakagawa, S.R. Mukai, H. Tamon, Adsorption–desorption characteristics of phenol and reactive dyes from aqueous solution on mesoporous activated carbon prepared from waste tires Water Research. ,vol. 39, pp. 1347- 1353 ,(2005) , 10.1016/J.WATRES.2004.12.044