Magnetic Chitosan–Iron(III) Hydrogel as a Fast and Reusable Adsorbent for Chromium(VI) Removal

作者: Zihan Yu , Xiaodan Zhang , Yuming Huang

DOI: 10.1021/IE400781N

关键词:

摘要: The magnetic chitosan–iron(III) hydrogel (MCh-Fe) was synthesized and characterized by SEM, TG, XRD, FT-IR used to remove toxic chromium(VI) (CrVI) from aqueous solution. adsorption of CrVI onto the MCh-Fe adsorbent fast could reach equilibrium in less than 30 min. well described pseudo-second-order rate model. isotherm better matched with Langmuir an endothermic spontaneous process. loading capacity on remained at a high level even after five cycles, showing that can be for repeated removal. Column results indicated below 0.5 mg L–1 found effluent up about 350 bed volumes two wastewaters containing 115.0 5.6 CrVI, respectively. removal mechanism also investigated.

参考文章(59)
Tzu-Yang Hsien, Gregory L. Rorrer, Heterogeneous Cross-Linking of Chitosan Gel Beads: Kinetics, Modeling, and Influence on Cadmium Ion Adsorption Capacity Industrial & Engineering Chemistry Research. ,vol. 36, pp. 3631- 3638 ,(1997) , 10.1021/IE9701579
Ibiba D. Harry, Basu Saha, Iain W. Cumming, Effect of Electrochemical Reduction and Oxidation of a Viscose Rayon Based Activated Carbon Cloth for Cr(VI) Sorption from Aqueous Solution Industrial & Engineering Chemistry Research. ,vol. 47, pp. 6734- 6741 ,(2008) , 10.1021/IE0711933
Veera M Boddu, Krishnaiah Abburi, Jonathan L Talbott, Edgar D Smith, None, Removal of hexavalent chromium from wastewater using a new composite chitosan biosorbent. Environmental Science & Technology. ,vol. 37, pp. 4449- 4456 ,(2003) , 10.1021/ES021013A
Anjali Gupta, Vivek Singh Chauhan, Nalini Sankararamakrishnan, Preparation and evaluation of iron–chitosan composites for removal of As(III) and As(V) from arsenic contaminated real life groundwater Water Research. ,vol. 43, pp. 3862- 3870 ,(2009) , 10.1016/J.WATRES.2009.05.040
Ana Claudia Zimmermann, Ariany Mecabô, Tathyane Fagundes, Clovis Antonio Rodrigues, Adsorption of Cr(VI) using Fe-crosslinked chitosan complex (Ch-Fe) Journal of Hazardous Materials. ,vol. 179, pp. 192- 196 ,(2010) , 10.1016/J.JHAZMAT.2010.02.078
Chensi Shen, Yu Shen, Yuezhong Wen, Hongyu Wang, Weiping Liu, Fast and highly efficient removal of dyes under alkaline conditions using magnetic chitosan-Fe(III) hydrogel Water Research. ,vol. 45, pp. 5200- 5210 ,(2011) , 10.1016/J.WATRES.2011.07.018
Dikla Zadaka, Adi Radian, Yael G. Mishael, Applying zeta potential measurements to characterize the adsorption on montmorillonite of organic cations as monomers, micelles, or polymers. joint international conference on information sciences. ,vol. 352, pp. 171- 177 ,(2010) , 10.1016/J.JCIS.2010.08.010