A ferrocene-perfluoroarene molecular complex

作者: Christopher M. Beck , Juan Burdeniuc , Robert H. Crabtree , Arnold L. Rheingold , Glenn P.A. Yap

DOI: 10.1016/S0020-1693(97)05999-9

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摘要: Abstract Perfluorophenanthrene and decamethylferrocene cocrystallize as a molecular adduct in monoclinic space group P21/c with = 8.842(2), b 11.262(1), c 30.695(8) A, β 95.89(2)°, V 3040.3(8) A3, Z 4. The structure was refined to R 0.0537 for 1567 observed reflections. perfluoroarene is twisted chiral; the crystal racemate, however.

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