Preparation of SnO2/graphene nanocomposite and its application to the catalytic epoxidation of alkenes with H2O2

作者: Min Liu , Xiaozhong Wang , Yingqi Chen , Liyan Dai

DOI: 10.1039/C5RA11285K

关键词:

摘要: The in situ growth of SnO2 nanoparticles on graphene have been achieved via a hydrothermal method and the nanocomposites were used as an efficient catalyst for epoxidation alkenes with aqueous hydrogen peroxide nitrile based systems first time. Furthermore, SnO2/graphene could be readily recovered reused at least ten consecutive cycles without significant loss activity selectivity.

参考文章(33)
Weiguo Zheng, Rong Tan, Lili Zhao, Yaju Chen, Chuanwu Xiong, Donghong Yin, Mn2+/graphene oxide nanocomposite efficiently catalyzes the epoxidation of alkenes with H2O2 RSC Advances. ,vol. 4, pp. 11732- 11739 ,(2014) , 10.1039/C3RA47183G
Vasant R. Choudhary, Rani Jha, Prabhas Jana, Epoxidation of styrene by TBHP to styrene oxide using barium oxide as a highly active/selective and reusable solid catalyst Green Chemistry. ,vol. 8, pp. 689- 690 ,(2006) , 10.1039/B604937K
Unnikrishnan R Pillai, Endalkachew Sahle-Demessie, Rajender S Varma, Microwave-expedited olefin epoxidation over hydrotalcites using hydrogen peroxide and acetonitrile Tetrahedron Letters. ,vol. 43, pp. 2909- 2911 ,(2002) , 10.1016/S0040-4039(02)00426-4
Xiaomei Chen, Genghuang Wu, Jinmei Chen, Xi Chen, Zhaoxiong Xie, Xiaoru Wang, Synthesis of "clean" and well-dispersive Pd nanoparticles with excellent electrocatalytic property on graphene oxide. Journal of the American Chemical Society. ,vol. 133, pp. 3693- 3695 ,(2011) , 10.1021/JA110313D
Ilham Kirm, Francesc Medina, Xavier Rodrı́guez, Yolanda Cesteros, Pilar Salagre, Jesús Sueiras, Epoxidation of styrene with hydrogen peroxide using hydrotalcites as heterogeneous catalysts Applied Catalysis A-general. ,vol. 272, pp. 175- 185 ,(2004) , 10.1016/J.APCATA.2004.05.039
Graeme Williams, Brian Seger, Prashant V. Kamat, TiO2-Graphene Nanocomposites. UV-Assisted Photocatalytic Reduction of Graphene Oxide ACS Nano. ,vol. 2, pp. 1487- 1491 ,(2008) , 10.1021/NN800251F
EunJoo Yoo, Tatsuhiro Okata, Tornoki Akita, Masanori Kohyama, Junji Nakamura, Itaru Honma, Enhanced Electrocatalytic Activity of Pt Subnanoclusters on Graphene Nanosheet Surface Nano Letters. ,vol. 9, pp. 2255- 2259 ,(2009) , 10.1021/NL900397T
G. Grigoropoulou, J. H. Clark, J. A. Elings, Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant Green Chemistry. ,vol. 5, pp. 1- 7 ,(2003) , 10.1039/B208925B