Ultrafast formation of nonemissive species via intermolecular interaction in single crystals of conjugated molecules.

作者: M. A. Loi , A. Mura , G. Bongiovanni , Q. Cai , C. Martin

DOI: 10.1103/PHYSREVLETT.86.732

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摘要: We investigate the influence of interchain interactions on photoluminescence processes in a sexithiophene single crystal by applying hydrostatic pressure. perform transient spectroscopy time domain 100 fs for pressures up to 60 kbar. The combined use steady-state and time-resolved optical spectroscopies allows us show that pressure-induced quenching is caused an ultrafast (approximately fs) formation intermolecular species.

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