Rhodium(iii)-catalyzed cascade oxidative annulation reactions of aryl imidazolium salts with alkynes involving multiple C–H bond activation

作者: Qingmei Ge , Bin Li , Haibin Song , Baiquan Wang

DOI: 10.1039/C5OB00823A

关键词:

摘要: The cascade oxidative annulation reactions of aryl imidazolium salts with alkynes proceed efficiently in the presence of [Cp*RhCl2]2 and Cu(OAc)2·H2O to give substituted imidazo[1,2-a]-quinolinium salts and benzo[ij]imidazo[2,1,5-de]quinolizinium salts.

参考文章(105)
Kevin M. Guthrie, Alexis D.C. Parenty, Louise V. Smith, Leroy Cronin, Alan Cooper, Microcalorimetry of interaction of dihydro-imidazo-phenanthridinium (DIP)-based compounds with duplex DNA. Biophysical Chemistry. ,vol. 126, pp. 117- 123 ,(2007) , 10.1016/J.BPC.2006.05.006
Bin Li, Nuancheng Wang, Yujie Liang, Shansheng Xu, Baiquan Wang, Ruthenium-Catalyzed Pyrrole Synthesis via Oxidative Annulation of Enamides and Alkynes Organic Letters. ,vol. 15, pp. 136- 139 ,(2013) , 10.1021/OL303159H
Craig J. Richmond, Alexis D. C. Parenty, Yu-Fei Song, Graeme Cooke, Leroy Cronin, Realization of a "Lockable" molecular switch via pH- and redox-modulated cyclization Journal of the American Chemical Society. ,vol. 130, pp. 13059- 13065 ,(2008) , 10.1021/JA803338M
Bin Li, Jianfeng Ma, Nuancheng Wang, Huiliang Feng, Shansheng Xu, Baiquan Wang, Ruthenium-catalyzed oxidative C-H bond olefination of N-methoxybenzamides using an oxidizing directing group. Organic Letters. ,vol. 14, pp. 736- 739 ,(2012) , 10.1021/OL2032575
F. Ekkehardt Hahn, Mareike C. Jahnke, Heterocyclic Carbenes: Synthesis and Coordination Chemistry Angewandte Chemie. ,vol. 47, pp. 3122- 3172 ,(2008) , 10.1002/ANIE.200703883
Liangbo Zhu, Peng Guo, Gaocan Li, Jingbo Lan, Rugang Xie, Jingsong You, Simple Copper Salt-Catalyzed N-Arylation of Nitrogen-Containing Heterocycles with Aryl and Heteroaryl Halides The Journal of Organic Chemistry. ,vol. 72, pp. 8535- 8538 ,(2007) , 10.1021/JO0712289
Weijia Xie, Jie Yang, Baiquan Wang, Bin Li, Regioselective Ortho Olefination of Aryl Sulfonamide via Rhodium-Catalyzed Direct C–H Bond Activation Journal of Organic Chemistry. ,vol. 79, pp. 8278- 8287 ,(2014) , 10.1021/JO5015239
Bin Li, Huiliang Feng, Nuancheng Wang, Jianfeng Ma, Haibin Song, Shansheng Xu, Baiquan Wang, Ruthenium-catalyzed oxidative coupling/cyclization of isoquinolones with alkynes through C-H/N-H activation: mechanism study and synthesis of dibenzo[a,g]quinolizin-8-one derivatives. Chemistry: A European Journal. ,vol. 18, pp. 12873- 12879 ,(2012) , 10.1002/CHEM.201201862
Alexis D. C. Parenty, Louise V. Smith, Kevin M. Guthrie, De-Liang Long, Jane Plumb, Robert Brown, Leroy Cronin, Highly stable phenanthridinium frameworks as a new class of tunable DNA binding agents with cytotoxic properties. Journal of Medicinal Chemistry. ,vol. 48, pp. 4504- 4506 ,(2005) , 10.1021/JM050320Z