Biosynthèse de L'α-spinastérol à partir du méthylène-24 dihydrolanostérol par l'épinard Spinacea oleracea

作者: Michel Devys , Antonio Alcaide , Michel Barbier , Edgar Lederer

DOI: 10.1016/S0031-9422(00)88236-9

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摘要: Resume Apres application de methylene-24[23,25-3H3] dihydrolanosterol (I) a des feuilles d'epinard Spinacea oleracea, on isole un melange sterols radioactifs contenant environ 42 pour cent d'α-spinasterol (II). Cette experience confirme qu'une substance ayant methylene en 24 peut etre le substrat la deuxieme etape C-methylation, conduisant chaine laterale ethylidene, ou ethyle phytosterols.

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