Comparison between fixed fluidized bed (FFB) and batch fluidized bed reactors in the evaluation of FCC catalysts

作者: Francisco Passamonti , Gabriela de la Puente , William Gilbert , Edisson Morgado , Ulises Sedran

DOI: 10.1016/J.CEJ.2011.12.081

关键词:

摘要: Abstract The laboratory reactors ACE fixed fluidized bed FFB and batch CREC Riser Simulator were compared in the conversion of two commercial vacuum gas oil feedstocks (paraffinic aromatic types) over equilibrium FCC catalysts (octane-barrel resid under similar conditions. Reaction temperatures 510 540 °C catalyst to mass ratios from 4 9 unit, with time on stream varying 112 50 s, 6.35 Simulator, reaction times ranging 5 25 s. results contrasted some cases those a DCR circulating pilot plant unit at 540 °C. When different product yields considered, same ranking was observed both whole, differences between particularly being more perceptible reactor. reactor showed linear yield curve for gasoline, which facilitated analysis comparisons; this case, an overcracking regime not shown, like case LCO curves defined developed clearly Coke very high reactor, typical confined beds continuous feed reactants, while they range units. complementing potential evaluation process.

参考文章(44)
P. O'connor, M. B. Hartkamp, A microscale simulation test for FCC development Preprints-American Chemical Society Division of Petroleum Chemistry. ,vol. 33, pp. 656- 662 ,(1988)
W.H. Humes, Arco's updated cat-cracking pilot unit Chem. Eng. Prog.; (United States). ,(1983)
Francisco J. Passamonti, Gabriela de la Puente, Ulises Sedran, Laboratory evaluation of FCC commercial catalysts: Analysis of products of industrial importance Catalysis Today. ,vol. 133, pp. 314- 318 ,(2008) , 10.1016/J.CATTOD.2007.12.123
Luis Antònio S. Casali, Sònia D.F. Rocha, Maria Laura A. Passos, Raquel Bastiani, Ricardo D.M. Pimenta, Henrique S. Cerqueira, Chapter 11 Equilibrium FCC catalyst performance simulation based on mixtures of hydrothermal deactivated samples Studies in Surface Science and Catalysis. ,vol. 166, pp. 147- 162 ,(2007) , 10.1016/S0167-2991(07)80194-7
William R. Gilbert, Claudia A. Baptista, Andrea R. Pinho, Chapter 3 Exploring FCC flexibility to produce mid-distillates and petrochemicals Studies in Surface Science and Catalysis. ,vol. 166, pp. 31- 39 ,(2007) , 10.1016/S0167-2991(07)80186-8
George W. Young, Chapter 8 Realistic Assessment of FCC Catalyst Performance in the Laboratory Studies in Surface Science and Catalysis. ,vol. 76, pp. 257- 292 ,(1993) , 10.1016/S0167-2991(08)63831-8
E.L. Moorehead, J.B. McLean, W.A. Cronkright, Chapter 7 Microactivity Evaluation of FCC Catalysts in the Laboratory: Principles, Approaches and Applications Studies in Surface Science and Catalysis. ,vol. 76, pp. 223- 255 ,(1993) , 10.1016/S0167-2991(08)63830-6
Siauw H. Ng, Adrian Humphries, Craig Fairbridge, Yuxia Zhu, Chandra Khulbe, Thomas Y.R. Tsai, Fuchen Ding, Jean-Pierre Charland, Sok Yui, Comparisons of FCC product yields and qualities between reactors using Canadian heavy feeds Fuel Processing Technology. ,vol. 86, pp. 1335- 1350 ,(2005) , 10.1016/J.FUPROC.2005.01.020
Trond Myrstad, Hege Engan, Testing of resid FCC catalysts in MAT Applied Catalysis A-general. ,vol. 171, pp. 161- 165 ,(1998) , 10.1016/S0926-860X(98)00100-8
Y.G. Adewuyi, D.J. Klocke, J.S. Buchanan, Effects of high-level additions of ZSM-5 to a fluid catalytic cracking (FCC) RE-USY catalyst Applied Catalysis A: General. ,vol. 131, pp. 121- 133 ,(1995) , 10.1016/0926-860X(95)00124-7