Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation.
作者： Timothy J. Brown , Dieter Weber , Michel R. Gagné , Ross A. Widenhoefer
DOI: 10.1021/JA303844H
关键词:
摘要: Mechanistic investigation of gold(I)-catalyzed intramolecular allene hydroalkoxylation established a mechanism involving rapid and reversible C–O bond formation followed by turnover-limiting protodeauration from mono(gold) vinyl complex. This on-cycle pathway competes with catalyst aggregation an off-cycle bis(gold)
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