Synthesis and properties of bridged phthalocyaninatoiron(II) complexes with bidentate aliphatic isocyanides

摘要: Phthalocyaninatoiron(II) (PcFe) was reacted with several aliphatic 5, 10–13, alicyclic 14, and aromatic isocyanides 3, 4 to form monomeric 15–17 bridged oligomeric complexes 18–22. The syntheses of the from corresponding amines are described. All products were characterized by spectroscopic methods. coordination behaviour based on their properties is discussed. oligomers 18–22 show conductivities in low semiconducting region, but doping iodine between 10−5 10−2 S/cm obtained.