Chemistry of acetylenic ethers 68: Preparation of enynes by elimination of alcohol from acetylenic ethers

作者: L. Brandsma , P. P. Montijn , J. F. Arens

DOI: 10.1002/RECL.19630821116

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摘要: Acetylenic ethers of the types RCH2CCCH2OR′ and RCH2CH2CCOR′ have been converted into alkenynylides RCHCHCCNa alkoxides R′ONa by treatment with two moles sodamide in liquid ammonia.

参考文章(2)
G. Eglinton, E. R. H. Jones, B. L. Shaw, M. C. Whiting, Researches on acetylenic compounds. Part XLIII. A new method for the preparation of alkoxyacetylenes Journal of the Chemical Society (Resumed). pp. 1860- 1865 ,(1954) , 10.1039/JR9540001860