Analysis of the 4800-Å absorption band of Cs2 by the classical method

摘要: Abstract The broad absorption band in Cs 2 having peak intensity near 4800 A is analyzed through computational simulation of the experimental spectrum using classical method. absorption, which terminates a weak satellite at 5223 A, can be interpreted terms single transition from ground state ( R e = 4.65 ω 42 cm −1 ) to an upper T 20 470 , 33 and 5.28 A. absolute strength roughly consistent with published lifetime data, but its reliability limited by thermodynamic uncertainties stemming remaining uncertainty dissociation enegy. paper includes summary diatomic radiation relations pertinent analysis low-resolution spectra, brief discussion reduced potential method applied alkali dimer states.