Synthesis and Characterization of a Series of Edge-Sharing Octahedral−Tetrahedral−Octahedral Linear Trinuclear Complexes [M3(L1O)4]2+, Where M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+ and L1OH Is the “Heteroscorpionate” Ligand (2-Hydroxyphenyl)bis(pyrazolyl)methane

作者： Timothy C. Higgs , K. Spartalian , Charles J. O'Connor , Berthold F. Matzanke , Carl J. Carrano

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摘要: The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M3(L1...

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Synthesis and Characterization of a Series of Edge-Sharing Octahedral−Tetrahedral−Octahedral Linear Trinuclear Complexes [M3(L1O)4]2+, Where M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+ and L1OH Is the “Heteroscorpionate” Ligand (2-Hydroxyphenyl)bis(pyrazolyl)methane

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Synthesis and Characterization of a Series of Edge-Sharing Octahedral−Tetrahedral−Octahedral Linear Trinuclear Complexes [M3(L1O)4]2+, Where M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+ and L1OH Is the “Heteroscorpionate” Ligand (2-Hydroxyphenyl)bis(pyrazolyl)methane

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