Simultaneous improvement of piezoelectric and magnetic properties in diamagnetic ion modified BiFeO3 film

作者: A.K. Jena , J. Arout Chelvane , J. Mohanty

DOI: 10.1016/J.JALLCOM.2019.07.154

关键词:

摘要: Abstract Multiferroic B i F e O 3 (BFO) and 0.97 Y 0.03 0.95 S c 0.05 (BYFSO) films were fabricated on FTO coated glass substrate using sol-gel spin-coating technique. Y–Sc co-doping induces the structural distortion without changing crystal structure (rhombohedral: R3c) of BFO. The electrical magnetic properties co-doped film may tuned due to increase in grain particles size. high dielectric constant ( r = 290 ) low loss t a n δ 0.084 indicates improved insulating BYFSO film. Increase oxygen vacancy concentration is explained with leakage current density, which follows Ohmic-SCLC conduction mechanism. Switching 180 0 domains into non- (maximum 71 109 type) ensures ferrolectric piezoelectric enhance significantly saturation magnetization M s ), remanent are 9.45 m u / , 6.154  respectively at coercive H field 0.822 kOe. Room temperature multiferroic be useful for non-volatile RRAM memory application.

参考文章(27)
Gustau Catalan, James F. Scott, Physics and Applications of Bismuth Ferrite Advanced Materials. ,vol. 21, pp. 2463- 2485 ,(2009) , 10.1002/ADMA.200802849
Richard E. Eitel, Clive A. Randall, Thomas R. Shrout, Paul W. Rehrig, Wes Hackenberger, Seung-Eek Park, New High Temperature Morphotropic Phase Boundary Piezoelectrics Based on Bi(Me)O3?PbTiO3 Ceramics Japanese Journal of Applied Physics. ,vol. 40, pp. 5999- 6002 ,(2001) , 10.1143/JJAP.40.5999
T. Kawae, Y. Terauchi, H. Tsuda, M. Kumeda, A. Morimoto, Improved leakage and ferroelectric properties of Mn and Ti codoped BiFeO3 thin films Applied Physics Letters. ,vol. 94, pp. 112904- ,(2009) , 10.1063/1.3098408
Alexei Gruverman, Orlando Auciello, Jun Hatano, Hiroshi Tokumoto, Scanning force microscopy as a tool for nanoscale study of ferroelectric domains Ferroelectrics. ,vol. 184, pp. 11- 20 ,(1996) , 10.1080/00150199608230240
D. Wu, I. Kunishima, S. Roberts, A. Gruverman, Spatial variations in local switching parameters of ferroelectric random access memory capacitors Applied Physics Letters. ,vol. 95, pp. 092901- ,(2009) , 10.1063/1.3192354
Victor Moritz Goldschmidt, Die Gesetze der Krystallochemie Naturwissenschaften. ,vol. 14, pp. 477- 485 ,(1926) , 10.1007/BF01507527
Kun Ho Ahn, Sang Sub Kim, Sunggi Baik, Change of conduction mechanism by microstructural variation in Pt/(Ba,Sr)TiO3/Pt film capacitors Journal of Applied Physics. ,vol. 92, pp. 421- 425 ,(2002) , 10.1063/1.1484233
Guido W. Dietz, Wolfgang Antpöhler, Mareike Klee, Rainer Waser, Electrode influence on the charge transport through SrTiO3 thin films Journal of Applied Physics. ,vol. 78, pp. 6113- 6121 ,(1995) , 10.1063/1.360553
Ramesh Nath, Ying-Hao Chu, Nicholas A. Polomoff, Ramamoorthy Ramesh, Bryan D. Huey, High speed piezoresponse force microscopy: <1 frame per second nanoscale imaging Applied Physics Letters. ,vol. 93, pp. 072905- ,(2008) , 10.1063/1.2969045
Jiagang Wu, John Wang, Improved ferroelectric behavior in (110) oriented BiFeO3 thin films Journal of Applied Physics. ,vol. 107, pp. 034103- ,(2010) , 10.1063/1.3296226