On the role of hydrophobic Si-based protective coatings in limiting mortar deterioration

作者: G. Cappelletti , P. Fermo , F. Pino , E. Pargoletti , E. Pecchioni

DOI: 10.1007/S11356-015-4962-0

关键词:

摘要: In order to avoid both natural and artificial stone decay, mainly due the interaction with atmospheric pollutants (both gases such as NOx SO2 particulate matter), polymeric materials have been widely studied protective coatings enable limit penetration of fluids into bulk material. current work, an air hardening calcic lime mortar (ALM) a hydraulic (HLM) were used substrates, commercially available Si-based resins (Alpha®SI30 Silres®BS16) adopted agents give hydrophobicity features stones. Surface properties their performance hydrophobic using different techniques contact angle measurements, capillary absorption test, mercury intrusion porosimetry, surface free energy, colorimetric measurements water vapour permeability tests. Finally, some exposure tests UV radiation real polluted environments (a city centre urban background site) carried out during wintertime period (when concentrations main are higher) in study durability coating systems applied. The effectiveness two commercial reducing salt formation (sulphate nitrate), induced by mortars pollutants, was demonstrated case HLM mortar.

参考文章(35)
Elena Pecchioni, Emma Cantisani, Fabio Fratini, The ancient mortars, an attestation of the material culture: the case of Florence ,(2006)
Maria Zielecka, Elżbieta Bujnowska, Silicone-containing polymer matrices as protective coatings: Properties and applications Progress in Organic Coatings. ,vol. 55, pp. 160- 167 ,(2006) , 10.1016/J.PORGCOAT.2005.09.012
C. M. Belfiore, G. V. Fichera, M. F. La Russa, A. Pezzino, S. A. Ruffolo, G. Galli, D. Barca, A Multidisciplinary Approach for the Archaeometric Study of Pozzolanic Aggregate in Roman Mortars: The Case of Villa dei Quintili (Rome, Italy) Archaeometry. ,vol. 57, pp. 269- 296 ,(2015) , 10.1111/ARCM.12085
Marc Mahy, Luc Van Eycken, André Oosterlinck, Evaluation of Uniform Color Spaces Developed after the Adoption of CIELAB and CIELUV Color Research and Application. ,vol. 19, pp. 105- 121 ,(1994) , 10.1111/J.1520-6378.1994.TB00070.X
Peter Brimblecombe, The effects of air pollution on the built environment Imperial College Press. ,(2003) , 10.1142/P243
Paulina Faria, Fernando Henriques, Vasco Rato, None, Comparative evaluation of lime mortars for architectural conservation Journal of Cultural Heritage. ,vol. 9, pp. 338- 346 ,(2008) , 10.1016/J.CULHER.2008.03.003
N. Ghedini, I. Ozga, A. Bonazza, M. Dilillo, H. Cachier, C. Sabbioni, Atmospheric aerosol monitoring as a strategy for the preventive conservation of urban monumental heritage: The Florence Baptistery Atmospheric Environment. ,vol. 45, pp. 5979- 5987 ,(2011) , 10.1016/J.ATMOSENV.2011.08.001
P. Fermo, G. Cappelletti, N. Cozzi, G. Padeletti, S. Kaciulis, M. Brucale, M. Merlini, Hydrophobizing coatings for cultural heritage. A detailed study of resin/stone surface interaction Applied Physics A. ,vol. 116, pp. 341- 348 ,(2014) , 10.1007/S00339-013-8127-Z
Marie Jackson, Fabrizio Marra, Roman Stone Masonry: Volcanic Foundations of the Ancient City American Journal of Archaeology. ,vol. 110, pp. 403- 436 ,(2006) , 10.3764/AJA.110.3.403