Poly(vinylpyrrolidone) tailored porous ceria as a carbon-free support for methanol electrooxidation
作者： Benfeng Lin , Zhao Lei , Feng Xu , Niancai Cheng , Shichun Mu
DOI: 10.1016/J.ELECTACTA.2018.09.006
关键词:
摘要: Abstract The inevitable corrosion of carbon support under operating condition direct methanol fuel cells significantly undermines the activity and durability Pt catalyst. Carbon-free materials with acceptable electronic conductivity, stability, co-functionality are promising alternative supports. We used poly(vinylpyrrolidone) as skeleton to prepare porous ceria for carbon-free support. has very high concentration oxygen vacancies, which plays key roles in: i) narrowing band gap improving conductivity; ii) catalytic performance. better electrooxidation achieved on supported
sci-hub.se 参考文章(59)
Jianbing Zhu, Meiling Xiao, Xiao Zhao, Changpeng Liu, Wei Xing, Titanium dioxide encapsulated in nitrogen-doped carbon enhances the activity and durability of platinum catalyst for Methanol electro-oxidation reaction Journal of Power Sources. ,vol. 292, pp. 78- 86 ,(2015) , 10.1016/J.JPOWSOUR.2015.05.041
Takanori Tamaki, Hidenori Kuroki, Shun Ogura, Teruaki Fuchigami, Yoshitaka Kitamoto, Takeo Yamaguchi, Connected nanoparticle catalysts possessing a porous, hollow capsule structure as carbon-free electrocatalysts for oxygen reduction in polymer electrolyte fuel cells Energy and Environmental Science. ,vol. 8, pp. 3545- 3549 ,(2015) , 10.1039/C5EE02450A
Fengcai Lei, Yongfu Sun, Katong Liu, Shan Gao, Liang Liang, Bicai Pan, Yi Xie, Oxygen vacancies confined in ultrathin indium oxide porous sheets for promoted visible-light water splitting. Journal of the American Chemical Society. ,vol. 136, pp. 6826- 6829 ,(2014) , 10.1021/JA501866R
Haifeng Lv, Shichun Mu, Nano-ceramic support materials for low temperature fuel cell catalysts Nanoscale. ,vol. 6, pp. 5063- 5074 ,(2014) , 10.1039/C4NR00402G
E.C. Hammel, O.L.-R. Ighodaro, O.I. Okoli, Processing and properties of advanced porous ceramics: An application based review Ceramics International. ,vol. 40, pp. 15351- 15370 ,(2014) , 10.1016/J.CERAMINT.2014.06.095
Junshu Wu, Jinshu Wang, Yucheng Du, Hongyi Li, Yilong Yang, Xinjian Jia, Chemically controlled growth of porous CeO2 nanotubes for Cr(VI) photoreduction Applied Catalysis B-environmental. ,vol. 174, pp. 435- 444 ,(2015) , 10.1016/J.APCATB.2015.03.040
Niancai Cheng, Mohammad Norouzi Banis, Jian Liu, Adam Riese, Xia Li, Ruying Li, Siyu Ye, Shanna Knights, Xueliang Sun, Extremely Stable Platinum Nanoparticles Encapsulated in a Zirconia Nanocage by Area-Selective Atomic Layer Deposition for the Oxygen Reduction Reaction Advanced Materials. ,vol. 27, pp. 277- 281 ,(2015) , 10.1002/ADMA.201404314
Hajime Hojo, Teruyasu Mizoguchi, Hiromichi Ohta, Scott D. Findlay, Naoya Shibata, Takahisa Yamamoto, Yuichi Ikuhara, Atomic Structure of a CeO2 Grain Boundary: The Role of Oxygen Vacancies Nano Letters. ,vol. 10, pp. 4668- 4672 ,(2010) , 10.1021/NL1029336
Keisuke Fugane, Toshiyuki Mori, Pengfei Yan, Takuya Masuda, Shunya Yamamoto, Fei Ye, Hideki Yoshikawa, Graeme Auchterlonie, John Drennan, Defect structure analysis of heterointerface between Pt and CeOx promoter on Pt electro-catalyst ACS Applied Materials & Interfaces. ,vol. 7, pp. 2698- 2707 ,(2015) , 10.1021/AM507754W
Sara Aranifard, Salai Cheettu Ammal, Andreas Heyden, On the importance of metal–oxide interface sites for the water–gas shift reaction over Pt/CeO2 catalysts Journal of Catalysis. ,vol. 309, pp. 314- 324 ,(2014) , 10.1016/J.JCAT.2013.10.012