Electrodeposition of zinc–tin alloys from deep eutectic solvents based on choline chloride
作者： Andrew P. Abbott , Glen Capper , Katy J. McKenzie , Karl S. Ryder
DOI: 10.1016/J.JELECHEM.2006.04.024
关键词:
摘要: Here we describe the electrolytic deposition of Zn, Sn and Zn/Sn alloys from a solution metal chloride salts separately in urea ethylene glycol/choline based ionic liquids. We show that kinetics thermodynamics differ aqueous processes qualitatively different phases, compositions morphologies are obtained for coatings liquid systems. have quantified electrochemical stripping responses using cyclic voltammetry together with compositional analysis SEM/EDAX X-ray diffraction. The differences rationalised terms speciation both Zn chlorides liquids been identified FAB mass spectrometry. Also demonstrate composite coatings, e.g. containing Al2O3 particles, can be these systems by virtue stable suspensions. This novel feature is function their relatively high viscosity.
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sci-hub.se 参考文章(21)
Ionic liquids as green solvents : progress and prospects American Chemical Society. ,(2003) , 10.1021/BK-2003-0856
弘幸 大野, Electrochemical aspects of ionic liquids Wiley Interscience. ,(2005)
Peter Wasserscheid, Thomas Welton, Ionic Liquids in Synthesis ,(2002)
V.S. Vasantha, Malathy Pushpavanam, V.S. Muralidharan, A noncyanide bath for the electrodeposition of tin-zinc alloys Metal Finishing. ,vol. 94, pp. 60- 63 ,(1996) , 10.1016/0026-0576(96)83958-4
Andrew P. Abbott, Glen Capper, David L. Davies, Raymond K. Rasheed, Pragna Shikotra, Selective extraction of metals from mixed oxide matrixes using choline-based ionic liquids. Inorganic Chemistry. ,vol. 44, pp. 6497- 6499 ,(2005) , 10.1021/IC0505450
A.P. Abbott, G. Capper, B.G. Swain, D.A. Wheeler, Electropolishing of stainless steel in an ionic liquid Transactions of The Institute of Metal Finishing. ,vol. 83, pp. 51- 53 ,(2005) , 10.1179/002029605X17657
E. Guaus, J. Torrent-Burgués, Tin–zinc electrodeposition from sulphate–gluconate baths Journal of Electroanalytical Chemistry. ,vol. 549, pp. 25- 36 ,(2003) , 10.1016/S0022-0728(03)00249-3
Allen J Bard, Larry R Faulkner, Henry S White, Electrochemical Methods: Fundamentals and Applications ,(1980)
Andrew P. Abbott, David Boothby, Glen Capper, David L. Davies, Raymond K. Rasheed, Deep Eutectic Solvents Formed between Choline Chloride and Carboxylic Acids: Versatile Alternatives to Ionic Liquids Journal of the American Chemical Society. ,vol. 126, pp. 9142- 9147 ,(2004) , 10.1021/JA048266J
Jason P. Hallett, Tom Welton, Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Chemical Reviews. ,vol. 99, pp. 2071- 2083 ,(1999) , 10.1021/CR1003248