Synthesis of Biodegradable Materials and Chemical Sensors Via Romp

作者: Ezat Khosravi , Izabela Czelusniak , Georgi Grancharov , Ritu Kataky , Alan M. Kenwright

DOI: 10.1007/978-90-481-3278-2_17

关键词:

摘要: This chapter will aim to (A) demonstrate that ring opening metathesis polymerisation (ROMP) is a power tool in macromolecular engineering and (B) show the usefulness of ruthenium initiators synthesis highly functionalised macromolecules. It be shown combination these two important characteristics allows design polymers with novel topologies for target applications. The first example discussed polymeric biodegrabable materials controlled degradation. second characterisation ionophoric channels based on 7-oxanorbosrnenes, as chemical sensor.

参考文章(45)
Shui Yu Lu, Peter Quayle, Frank Heatley, Colin Booth, Stephen G. Yeates, John C. Padget, Aqueous ring-opening metathesis polymerization of exo,exo-2,3-bis(methoxymethyl)-7-oxanorbornene catalyzed by ruthenium trichloride Macromolecules. ,vol. 25, pp. 2692- 2697 ,(1992) , 10.1021/MA00036A020
Maria Ryner, Kajsa Stridsberg, Ann-Christine Albertsson, Henrik von Schenck, Mats Svensson, Mechanism of Ring-Opening Polymerization of 1,5-Dioxepan-2-one and l-Lactide with Stannous 2-Ethylhexanoate. A Theoretical Study Macromolecules. ,vol. 34, pp. 3877- 3881 ,(2001) , 10.1021/MA002096N
Peter Schwab, Robert H. Grubbs, Joseph W. Ziller, Synthesis and Applications of RuCl2(CHR‘)(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity Journal of the American Chemical Society. ,vol. 118, pp. 100- 110 ,(1996) , 10.1021/JA952676D
Hak Soo Choi, Tooru Ooya, Shintaro Sasaki, Nobuhiko Yui, Yuichi Ohya, Takao Nakai, Tatsuro Ouchi, Preparation and Characterization of Polypseudorotaxanes Based on Biodegradable Poly(l-lactide)/Poly(ethylene glycol) Triblock Copolymers Macromolecules. ,vol. 36, pp. 9313- 9318 ,(2003) , 10.1021/MA035200K
Hans K. Frensdorff, Stability constants of cyclic polyether complexes with univalent cations Journal of the American Chemical Society. ,vol. 93, pp. 600- 606 ,(1971) , 10.1021/JA00732A007
P. Lecomte, D. Mecerreyes, P. Dubois, A. Demonceau, A. F. Noels, R. Jérôme, Synthesis of poly(norbornene-g-ε-caprolactone) copolymers by sequential controlled ring opening polymerization Polymer Bulletin. ,vol. 40, pp. 631- 638 ,(1998) , 10.1007/S002890050301