Extraction of Fish Oil by Fractionation through Supercritical Carbon Dioxide
作者： R. Davarnejad , K. M. Kassim , A. Zainal , Suhairi A. Sata
DOI: 10.1021/JE800273C
关键词:
摘要: In the present research, solubility of fish oil in supercritical carbon dioxide was studied at temperatures (40, 50, 60, and 70) °C pressures (13.6, 20.4, 27.2) MPa. The fractionated samples collected were then esterified using methanol (with sodium methoxide catalyst). analyzed by GC to determine amount four fatty acid methyl ester (FAME) components extracted, namely, palmitate, oleate, EPA (5,8,11,14,17-eicosapentanoate), DHA (4,7,10,13,16,19-docosahexenoate). experimental results showed that highest (0.921 g oil/100 CO2) obtained optimum conditions 40 27.2 found be higher lower temperature fractionation time. Furthermore, average yield for combined total FAME 66 %. Methyl palmitate recorded value 30.5 % extraction c...
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sci-hub.se 参考文章(22)
Clemens von Schacky, The Effect of Dietary ω-3 Fatty Acids on Coronary Atherosclerosis Annals of Internal Medicine. ,vol. 130, pp. 554- 562 ,(1999) , 10.7326/0003-4819-130-7-199904060-00003
W. B. Nilsson, E. J. Gauglitz, J. K. Hudson, V. F. Stout, J. Spinelli, Fractionation of menhaden oil ethyl esters using supercritical fluid CO2 Journal of the American Oil Chemists' Society. ,vol. 65, pp. 109- 117 ,(1988) , 10.1007/BF02542560
Ragunath Bharath, Seichiro Yamane, Hiroshi Inomata, Tadafumi Adschiri, Kunio Arai, Phase equilibria of supercritical CO2 - fatty oil component binary systems Fluid Phase Equilibria. ,vol. 83, pp. 183- 192 ,(1993) , 10.1016/0378-3812(93)87021-R
Jean-Noël Jaubert, Pascale Borg, Lucie Coniglio, Danielle Barth, Phase equilibria measurements and modeling of EPA and DHA ethyl esters in supercritical carbon dioxide The Journal of Supercritical Fluids. ,vol. 20, pp. 145- 155 ,(2001) , 10.1016/S0896-8446(01)00062-6
Arne Staby, Jørgen Mollerup, Separation of constituents of fish oil using supercritical fluids: a review of experimental solubility, extraction, and chromatographic data Fluid Phase Equilibria. ,vol. 91, pp. 349- 386 ,(1993) , 10.1016/0378-3812(93)85109-Y
Fausto Gironi, Marco Maschietti, Separation of fish oils ethyl esters by means of supercritical carbon dioxide: Thermodynamic analysis and process modelling Chemical Engineering Science. ,vol. 61, pp. 5114- 5126 ,(2006) , 10.1016/J.CES.2006.03.041
V. Riha, G. Brunner, Separation of fish oil ethyl esters with supercritical carbon dioxide The Journal of Supercritical Fluids. ,vol. 17, pp. 55- 64 ,(2000) , 10.1016/S0896-8446(99)00038-8
Owen J. Catchpole, Jan-Christian von Kamp, John B. Grey, Extraction of squalene from shark liver oil in a packed column using supercritical carbon dioxide Industrial & Engineering Chemistry Research. ,vol. 36, pp. 4318- 4324 ,(1997) , 10.1021/IE9702237
N.A. Nik Norulaini, I.S. Md Zaidul, O. Anuar, A.K. Mohd. Omar, Supercritical enhancement for separation of lauric acid and oleic acid in palm kernel oil (PKO) Separation and Purification Technology. ,vol. 35, pp. 55- 60 ,(2004) , 10.1016/S1383-5866(03)00129-1
Hidenori Higashi, Yoshio Iwai, Yasuhiko Arai, Solubilities and diffusion coefficients of high boiling compounds in supercritical carbon dioxide Chemical Engineering Science. ,vol. 56, pp. 3027- 3044 ,(2001) , 10.1016/S0009-2509(01)00003-3