Isotope Effects and the Mechanism of Triazolinedione Ene Reactions. Aziridinium Imides Are Innocent Bystanders

作者: Daniel A. Singleton , Chao Hang

DOI: 10.1021/JA9933339

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摘要: Kinetic isotope effects were determined for the ene reactions of 4-phenyl-1,2,4-triazoline-2,5-dione with 2-methyl-2-butene and 2-methyl-1-pentene. In each case highly inverse (k H /k D …

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