Preparation, Crystal Structure and Properties of a Pentametallic 3-Ferrocenyl-2-crotonic acid-Bridged Copper（II） Complex
作者： Jia-Xiang Yang , Ze Zhang , Jie-Ying Wu , Yu-Peng Tian , Qing-Liang Liu
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摘要: The synthesis and characterization of the copper(ll) complex[ Cu2 ( OOCCH = C (CH3) Fc )3 phen ) 2 ] ClO4·2H2O 1 are reported. structure complex was determined by singlecrystal X-ray analysis. compound crystallizes in monoclinic system, space group Pc, with Z 2, a 1.2799(4) nm,b =0.9969(4) nm, c 2.5228 β 91.576(1)°. cationic part indicates penametallic core which three 3-ferrocenyl-2-crotonic acid salt (FCA) groups act as (O, O'') bridging ligands between two copper(II) ions squarepyramidal environment. Cyclic voltammetric experiments acetonitrile have been performed mainly to examine Fe(Ⅱ)→Fe(Ⅲ) one-electron oxidation FCA its complex. variable-temperature magnetic susceptibility measurements re-vealed very weak intramolecular anti-ferromagnetic coupling.Fitting parameters 2J -0.2 cm^-1, g 2.114, θ=0 K.
sci-hub.se 参考文章(31)
Grant A. McLachlan, Gary D. Fallon, Raymond L. Martin, Leone Spiccia, Synthesis, Structure and Properties of Five-Coordinate Copper(II) Complexes of Pentadentate Ligands with Pyridyl Pendant Arms Inorganic Chemistry. ,vol. 34, pp. 254- 261 ,(1995) , 10.1021/IC00105A041
Karen Bertoncello, Gary D. Fallon, Jonathan H. Hodgkin, Keith S. Murray, Exogenous bridging and nonbridging in copper(II) complexes of a binucleating 2,6-bis((N-methylpiperazino)methyl)-4-chlorophenolate ligand. Crystal structures and magnetic properties of bis(.mu.-acetato), dinitrito and bis(azido) complexes. Possible relevance to the type 3 depleted laccase active site Inorganic Chemistry. ,vol. 27, pp. 4750- 4758 ,(1988) , 10.1021/IC00299A014
James C. Barborak, Jeffrey M. Chance, Direct synthesis of ferrocenyl alcohols from aldehydes and ketones The Journal of Organic Chemistry. ,vol. 49, pp. 703- 704 ,(1984) , 10.1021/JO00178A027
Yuzo Nishida, Tadashi Tokii, Yutaka Mori, A novel µ-phenolato binuclear copper(II) complex where two basal planes are nearly orthogonal Journal of The Chemical Society, Chemical Communications. pp. 675- 676 ,(1988) , 10.1039/C39880000675
Gus J. Palenik, Crystal and molecular structure of diacetylferrocene Inorganic Chemistry. ,vol. 9, pp. 2424- 2430 ,(1970) , 10.1021/IC50093A008
Paul Nguyen, Paloma Gómez-Elipe, Ian Manners, Organometallic Polymers with Transition Metals in the Main Chain. Chemical Reviews. ,vol. 99, pp. 1515- 1548 ,(1999) , 10.1021/CR960113U
Nobumasa Kitajima, Kiyoshi Fujisawa, Yoshihiko Morooka, Koshiro Toriumi, .mu.-.eta.2:.eta.2-Peroxo binuclear copper complex, [Cu(HB(3,5-(Me2CH)2pz)3)]2(O2) Journal of the American Chemical Society. ,vol. 111, pp. 8975- 8976 ,(1989) , 10.1021/JA00206A062
A. Latif Abuhijleh, Clifton Woods, Syntheses and molecular structures of cis and trans monomeric ferrocenecarboxylatocopper(II) complexes with imidazole derivatives Journal of The Chemical Society-dalton Transactions. pp. 1249- 1252 ,(1992) , 10.1039/DT9920001249
Chensheng Li, Julio C. Medina, Glenn E. M. Maguire, Ernesto Abel, Jerry L. Atwood, George W. Gokel, Neutral Molecule Receptor Systems Using Ferrocene's “Atomic Ball Bearing” Character as the Flexible Element Journal of the American Chemical Society. ,vol. 119, pp. 1609- 1618 ,(1997) , 10.1021/JA9600284
George Christou, Spiros P. Perlepes, Eduardo Libby, Kirsten Folting, John C. Huffman, Robert J. Webb, David N. Hendrickson, Preparation and properties of the triply bridged, ferromagnetically coupled dinuclear copper(II) complexes [Cu2(OAc)3(bpy)2](ClO4) and [Cu2(OH)(H2O)(OAc)(bpy)2](ClO4)2 Inorganic Chemistry. ,vol. 29, pp. 3657- 3666 ,(1990) , 10.1021/IC00344A008