Thermogravimetric Analysis and Chemical Kinetics for Regeneration of Sodium and Potassium Carbonate Solid Sorbents
作者： Pilaiwan Chaiwang , Benjapon Chalermsinsuwan , Pornpote Piumsomboon
DOI: 10.1080/00986445.2015.1078796
关键词:
摘要: In this study, nonisothermal kinetic methods for the decomposition of potassium hydrogen carbonate (KHCO3) and sodium (NaHCO3) were investigated by thermogravimetry (TG) derivative (DTG). Four different heating rates measured to calculate order reaction (n), preexponential factor (A), activation energy (Ea) using four models: Kissinger–Akahira–Sunose (KAS), Flynn–Wall–Ozawa (FWO), Kim–Park, analytical methods. The results showed that method provided highly accurate compared with experimental data, whereas KAS, FWO, Kim–Park gave less due approximation employed equations. KHCO3 NaHCO3 was approximately 2. slightly higher than NaHCO3. obtained parameters from those then used chemical conversion further applications.
sci-hub.se 参考文章(27)
Wei Tang, Xin-Gui Li, Deyue Yan, Thermal decomposition kinetics of thermotropic copolyesters made from trans‐p‐hydroxycinnamic acid and p‐hydroxybenzoic acid Journal of Applied Polymer Science. ,vol. 91, pp. 445- 454 ,(2004) , 10.1002/APP.13103
Pavan K. Heda, David Dollimore, Kenneth S. Alexander, Dun Chen, Emmeline Law, Paul Bicknell, A method of assessing solid state reactivity illustrated by thermal decomposition experiments on sodium bicarbonate Thermochimica Acta. ,vol. 255, pp. 255- 272 ,(1995) , 10.1016/0040-6031(94)02154-G
Takeo Ozawa, A New Method of Analyzing Thermogravimetric Data Bulletin of the Chemical Society of Japan. ,vol. 38, pp. 1881- 1886 ,(1965) , 10.1246/BCSJ.38.1881
Paul J. Kramer, Carbon Dioxide Concentration, Photosynthesis, and Dry Matter Production BioScience. ,vol. 31, pp. 29- 33 ,(1981) , 10.2307/1308175
P. Behr, A. Maun, K. Deutgen, A. Tunnat, G. Oeljeklaus, K. Görner, Kinetic study on promoted potassium carbonate solutions for CO2 capture from flue gas Energy Procedia. ,vol. 4, pp. 85- 92 ,(2011) , 10.1016/J.EGYPRO.2011.01.027
Y. Liang, D. P. Harrison, R. P. Gupta, D. A. Green, W. J. McMichael, Carbon Dioxide Capture Using Dry Sodium-Based Sorbents Energy & Fuels. ,vol. 18, pp. 569- 575 ,(2004) , 10.1021/EF030158F
Seungdo Kim, Jae K. Park, Characterization of thermal reaction by peak temperature and height of DTG curves Thermochimica Acta. ,vol. 264, pp. 137- 156 ,(1995) , 10.1016/0040-6031(95)02316-T
Sunti Kongkitisupchai, Dimitri Gidaspow, Carbon dioxide capture using solid sorbents in a fluidized bed with reduced pressure regeneration in a downer Aiche Journal. ,vol. 59, pp. 4519- 4537 ,(2013) , 10.1002/AIC.14215
A. Yokozeki, Mark B. Shiflett, Christopher P. Junk, Liane M. Grieco, Thomas Foo, Physical and chemical absorptions of carbon dioxide in room-temperature ionic liquids. Journal of Physical Chemistry B. ,vol. 112, pp. 16654- 16663 ,(2008) , 10.1021/JP805784U
Haiping Yang, Rong Yan, Terence Chin, David Tee Liang, Hanping Chen, Chuguang Zheng, Thermogravimetric Analysis−Fourier Transform Infrared Analysis of Palm Oil Waste Pyrolysis Energy & Fuels. ,vol. 18, pp. 1814- 1821 ,(2004) , 10.1021/EF030193M