Viscoelastic properties of poly(vinyl alcohol) hydrogels and ferrogels obtained through freezing–thawing cycles

作者: Rebeca Hernández , Aurélie Sarafian , Daniel López , Carmen Mijangos

DOI: 10.1016/J.POLYMER.2004.05.061

关键词:

摘要: Abstract We report the preparation of poly(vinyl alcohol) (PVA) hydrogels obtained through freezing–thawing cycles. The viscoelastic properties these gels using parallel-plate shear mode were evaluated as a function temperature, time, degree swelling, concentration and number storage modulus was analyzed on basis theoretical model based scaling approach. These results provide additional evidence for non-crystalline nature structure PVA cryogels. Furthermore, ferrogels have been prepared from aqueous solutions ferrofluid materials evaluated. It is shown that variation with cannot be fitted classical theories what has attributed to small dimensions particles in magnetic interactions between particles.

参考文章(24)
C. A. Finch, Polyvinyl alcohol : developments Wiley. ,(1992)
Jean-Michel Guenet, Thermoreversible gelation of polymers and biopolymers Academic Press. ,(1992)
Robert F. Landel, Lawrence E. Nielsen, Mechanical Properties of Polymers and Composites ,(1993)
L. Deák, G. Bayreuther, L. Bottyán, E. Gerdau, J. Korecki, E. I. Kornilov, H. J. Lauter, O. Leupold, D. L. Nagy, A. V. Petrenko, V. V. Pasyuk-Lauter, H. Reuther, E. Richter, R. Röhloberger, E. Szilágyi, PURE NUCLEAR BRAGG REFLECTION OF A PERIODIC 56FE/57FE MULTILAYER Journal of Applied Physics. ,vol. 85, pp. 1- 7 ,(1999) , 10.1063/1.369470
Herbert Morawetz, Macromolecules in solution ,(1965)
Christophe Daniel, Christoph Dammer, Jean-Michel Guenet, On the definition of thermoreversible gels : the case of syndiotactic polystyrene Polymer. ,vol. 35, pp. 4243- 4246 ,(1994) , 10.1016/0032-3861(94)90604-1
D. López, C. Mijangos, M. E. Muñoz, A. Santamaría, Viscoelastic Properties of Thermoreversible Gels from Chemically Modified PVCs Macromolecules. ,vol. 29, pp. 7108- 7115 ,(1996) , 10.1021/MA9600973
Rebeca Hernandez, Daniel Lopez, Carmen Mijangos, Jean-Michel Guenet, A reappraisal of the ‘thermoreversible’ gelation of aqueous poly(vinyl alcohol) solutions through freezing–thawing cycles Polymer. ,vol. 43, pp. 5661- 5663 ,(2002) , 10.1016/S0032-3861(02)00470-6
Shauna R. Stauffer, Nikolaos A. Peppast, Poly (vinyl alcohol) hydrogels prepared by freezing-thawing cyclic processing Polymer. ,vol. 33, pp. 3932- 3936 ,(1992) , 10.1016/0032-3861(92)90385-A
M Krumova, D López, R Benavente, C Mijangos, J.M Pereña, Effect of crosslinking on the mechanical and thermal properties of poly(vinyl alcohol) Polymer. ,vol. 41, pp. 9265- 9272 ,(2000) , 10.1016/S0032-3861(00)00287-1