Thermal decomposition of flame-retarded high-impact polystyrene
作者： E Jakab , Md.A Uddin , T Bhaskar , Y Sakata
DOI: 10.1016/S0165-2370(03)00075-5
关键词:
摘要: The thermal decomposition of four high-impact polystyrene (HIPS) samples containing brominated flame retardants has been studied. Decabromodiphenyl ether (Br10-DPE) and decabromodibenzyl (Br10-DB) were used as two contained antimony trioxide (Sb2O3) synergist besides the additives. HIPS was studied by thermogravimetry/mass spectrometry (TG/MS), pyrolysis-gas chromatography/mass (Py-GC/MS) pyrolysis-mass (Py-MS). It established that additives themselves do not change temperature (PS). However, Sb2O3 reduces stability indicating initiates PS. Water styrene products detected during first stage from Sb2O3. Nevertheless, majority PS decomposes at a higher temperature. decompose different pathways. scission CC bonds, resulting in formation bromotoluenes, is most important reaction Br10-DB In contrast, Br10-DPE an intermolecular ring closure pathway producing dibenzofurans (DBF).
elsevier.com
sci-hub.se 参考文章(21)
Samuel Leo Madorsky, Thermal Degradation of Organic Polymers ,(1964)
J. Simon, T. Kántor, T. Kozma, E. Pungor, Thermal analysis of Sb2O3 /Organohalide-based flame retardants including atomic absorption detection of the evolved species Journal of Thermal Analysis and Calorimetry. ,vol. 25, pp. 57- 77 ,(1982) , 10.1007/BF01913054
W. Schnabel, G.F. Levchik, C.A. Wilkie, D.D. Jiang, S.V. Levchik, Thermal degradation of polystyrene, poly(1,4-butadiene) and copolymers of styrene and 1,4-butadiene irradiated under air or argon with 60Co-γ-rays Polymer Degradation and Stability. ,vol. 63, pp. 365- 375 ,(1999) , 10.1016/S0141-3910(98)00114-1
M. Wolf, M. Riess, D. Heitmann, M. Schreiner, H. Thoma, O. Vierle, R. van Eldik, Application of a purge and trap TDS-GC/MS procedure for the determination of emissions from flame retarded polymers. Chemosphere. ,vol. 41, pp. 693- 699 ,(2000) , 10.1016/S0045-6535(99)00459-2
Ayako Torikai, Takahiro Kobatake, Fumio Okisaki, Hideo Shuyama, Photodegradation of polystyrene containing flame-retardants: wavelength sensitivity and efficiency of degradation Polymer Degradation and Stability. ,vol. 50, pp. 261- 267 ,(1995) , 10.1016/0141-3910(95)00143-3
Md.Azhar Uddin, Thallada Bhaskar, Jun Kaneko, Akinori Muto, Yusaku Sakata, Toshiki Matsui, Dehydrohalogenation during pyrolysis of brominated flame retardant containing high impact polystyrene (HIPS-Br) mixed with polyvinylchloride (PVC) ☆ Fuel. ,vol. 81, pp. 1819- 1825 ,(2002) , 10.1016/S0016-2361(02)00109-6
Hiroaki Sato, Kiyotaka Kondo, Shin Tsuge, Hajime Ohtani, Nobuyuki Sato, Mechanisms of thermal degradation of a polyester flame-retarded with antimony oxide/brominated polycarbonate studied by temperature-programmed analytical pyrolysis Polymer Degradation and Stability. ,vol. 62, pp. 41- 48 ,(1998) , 10.1016/S0141-3910(97)00259-0
D. Price, G.J. Milnes, C. Lukas, A.M. Phillips, Pyrolysis studies of flame retarded plastic systems Journal of Analytical and Applied Pyrolysis. ,vol. 11, pp. 499- 510 ,(1987) , 10.1016/0165-2370(87)85049-0
R. Dumler, D. Lenoir, H. Thoma, O. Hutzinger, Thermal formation of polybrominated dibenzofurans from decabromodiphenyl ether in a polybutylene-terephthalate polymer matrix Journal of Analytical and Applied Pyrolysis. ,vol. 16, pp. 153- 158 ,(1989) , 10.1016/0165-2370(89)85014-4
W. Klusmeier, R. Sonnemann, K.-H. Ohrbach, A. Kettrup, Investigations of the combustion products of flame-protected impact resistant polystyrene Thermochimica Acta. ,vol. 112, pp. 75- 79 ,(1987) , 10.1016/0040-6031(87)88083-8