Kinetics and Mechanism for the Reaction of Ozone with Cycloalkenes

摘要: Rate constants for the reaction of O3 with a series cycloalkenes have been investigated over atmospherically important temperature range 240–324 K and 1 atmosphere total pressure. The rate data obtained in present study are discussed terms substituent effects ring strain these cyclic systems. Hydroxyl radical formation yields were determined reactions at 298 ± 2 an air. results indicate that OH close to structurally similar molecule cis-2-butene providing support suggestion O3-alkene systems depend largely on degree alkyl group substitution double bond site.