Generalized Synthesis of EAs [E = Fe, Co, Mn, Cr] Nanostructures and Investigating Their Morphology Evolution

摘要: This paper illustrates a novel route for the synthesis of nanostructured transition metal arsenides including those FeAs, CoAs, MnAs, and CrAs through generalized protocol. The key feature method is use one-step hot-injection clever combination precursors which are low-melting highly reactive such as carbonyls triphenylarsine in solventless setup. also facilitates formation one-dimensional nanostructures we move across periodic table from to CoAs. chemical basis this reaction simple redox chemistry between metals, wherein oxidized elemental state () lieu reduction As3