The Enantioselective Morita–Baylis–Hillman Reaction and Its Aza Counterpart
作者： Géraldine Masson , Christopher Housseman , Jieping Zhu
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摘要: The development of asymmetric Morita-Baylis-Hillman (MBH) reactions has evolved dramatically over the past few years, parallel to emerging concept bifunctional organocatalysis. Whereas organocatalysis is starting compete with metal-based catalysis in several important organic transformations, MBH reaction belongs a group prototypical which organocatalysts already display superiority their counterparts. This Minireview summarizes recent mechanistic insights and advances design synthesis small molecules for enantioselective aza-MBH reactions.
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