Polymer-Supported Phosphoric, Phosphonic and Phosphinic Acids-From Synthesis to Properties and Applications in Separation Processes.

摘要: Efficient separation technologies are crucial to the environment and world economy. The challenge posed scientists is how engineer selectivity towards a targeted substrate, especially from multicomponent solutions. Polymer-supported reagents have gained lot of attention in this context, as they eliminate inconveniences concerning widely used solvent extraction techniques. Nevertheless, choice an appropriate ligand for immobilization may be derived behavior soluble compounds under conditions. Organophosphorus play significant role science technology. features possess, such variable oxidation states, multivalence, asymmetry metal-binding properties, highlight their status unique versatile class compounds, capable selective separations proceeding through different mechanisms. This review provides detailed survey polymers containing phosphoric, phosphonic phosphinic acid functionalities side chain covers main advances preparation application these materials science, including most relevant synthesis routes (Arbuzov, Perkow, Mannich, Kabachnik-Fields reactions, etc.), well stages development organophosphorus resins important achievements field.