Supercritical extraction of polymers from printed circuit boards using CO2 and ethanol

作者: Camila O Calgaro , Diego F Schlemmer , Mariana M Bassaco , Guilherme L Dotto , Eduardo H Tanabe

DOI: 10.1016/J.JCOU.2017.10.020

关键词:

摘要: Abstract The printed circuit boards are the fundamental components of waste electrical and electronic equipment (WEEE). PCBs stand out due to amount metals in their composition as well for complex heterogeneous constitution that make recycling difficult. In this context, aims study was evaluate application supercritical CO2 modified with ethanol order remove polymers contained from discarded mobile phones. were characterized an evaluation extraction performed through experimental design. characterization showed 64.02 wt% metals, 20.51 wt% ceramics 15.47 wt% polymers. fractional factorial design 69.53 wt% present extracted, at 170 °C 7.5 MPa. As remaining no longer covering they could be more easily leached therefore effectively recovered.

参考文章(45)
Abdel mnim Altwaiq, Marion Wolf, Rudi van Eldik, Extraction of brominated flame retardants from polymeric waste material using different solvents and supercritical carbon dioxide Analytica Chimica Acta. ,vol. 491, pp. 111- 123 ,(2003) , 10.1016/S0003-2670(03)00785-2
M. Somasundaram, R. Saravanathamizhan, C. Ahmed Basha, V. Nandakumar, S. Nathira Begum, T. Kannadasan, Recovery of copper from scrap printed circuit board: modelling and optimization using response surface methodology Powder Technology. ,vol. 266, pp. 1- 6 ,(2014) , 10.1016/J.POWTEC.2014.06.006
Angela C Kasper, Guilherme BT Berselli, Bruno D Freitas, Jorge AS Tenório, Andréa M Bernardes, Hugo M Veit, None, Printed wiring boards for mobile phones: characterization and recycling of copper. Waste Management. ,vol. 31, pp. 2536- 2545 ,(2011) , 10.1016/J.WASMAN.2011.08.013
Hongtao Wang, Maya Hirahara, Motonobu Goto, Tsutomu Hirose, Extraction of flame retardants from electronic printed circuit board by supercritical carbon dioxide Journal of Supercritical Fluids. ,vol. 29, pp. 251- 256 ,(2004) , 10.1016/S0896-8446(03)00073-1
Miguel Herrero, Jose A. Mendiola, Alejandro Cifuentes, Elena Ibáñez, Supercritical fluid extraction: Recent advances and applications Journal of Chromatography A. ,vol. 1217, pp. 2495- 2511 ,(2010) , 10.1016/J.CHROMA.2009.12.019
Qingjie Guo, Xuehai Yue, Minghua Wang, Yongzhuo Liu, Pyrolysis of scrap printed circuit board plastic particles in a fluidized bed Powder Technology. ,vol. 198, pp. 422- 428 ,(2010) , 10.1016/J.POWTEC.2009.12.011