Reversible dynamic isomerism change in the solid state, from Bi4I16 clusters to BiI4 1D chains in L-cystine based hybrids: templating effect of cations in iodobismuthate network formation.
作者： Wenhua Bi , Nicolas Mercier
DOI: 10.1039/B812588K
关键词:
摘要: The dehydration of a iodobismuthate hybrid built up from Bi4I16clusters and protonated L-cystine molecules involves an unprecedented reversible dynamic structural change in the solid state leading to 1D BiI4 chains helical molecular chains, highlighting templating effect cations formation network.
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