Role of adsorption complexes in catalytic acceleration of heterogeneous reactions
作者： V. F. Kharlamov , F. V. Kharlamov
DOI: 10.1134/S1027451009040284
关键词:
摘要: The universal equation that imposes restrictions on the kinetics of heterogeneous chemical reactions has been derived. A method studying participation chemisorbed or physisorbed gas molecules in proposed. It shown reaction rate is independent degree occupation catalyst surface by reactants as long product formed complexes and molecules. found formation CO2 CO+ O → 2CO + O2 2CO2 participated particles oxygen atoms CO
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