Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3
作者： Alexander Hinz , Axel Schulz , Alexander Villinger
DOI: 10.1039/C5CC04355G
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摘要: The attempted preparation of the biradicaloid [E(μ-NTer)]2 (E = Sb, Bi) yielded salts anion [(TerN)2E]−. These heteroatom allyl analogues could be further utilized in reaction with pnictogen(III) chlorides to form first 1,3-dichloro-1-bisma-3-stiba-2,4-diazane [ClSb(μ-NTer)2BiCl].
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